Department of Applied Chemistry, Graduate School of Engineering Osaka University MINAKATA Lab. Synthetic Organic Chemistry Research Group

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論文 Publication List at MINAKATA Lab.

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"CO2-Induced Amidobromination of Olefins with Bromamine-T"
Junpei Hayakawa, Mitsuhiro Kuzuhara, and Satoshi Minakata*
Org. Biomol. Chem. 2010, 8, 1424-1430. DOI: 10.1039/b923253m

Abstract: The carbon dioxide (CO2)-induced amidobromination of olefins with bromamine-T is described. The method can be used in reactions with a wide range of olefins, both aromatic and aliphatic, as well as electron-rich and deficient olefins, leading to the regioselective formation of amidobrominated compounds.

"Atmospheric CO2 Fixation by Unsaturated Alcohols Using t-BuOI under Neutral Conditions"
Satoshi Minakata,* Itsuro Sasaki, and Toshihiro Ide
Angew. Chem., Int. Ed. 2010, 49, 1309-1311.DOI: 10.1002/anie.200906352

* Selected as a "Hot paper"! see the detail
* Selected as one of the top 10 Selected Papers in Annual Report of OSAKA Univ.! 2009-2010 link)

Abstract: Reaction of CO2 with unsaturated alcohols and tBuOI to form cyclic carbonates leads to fixation of the greenhouse gas. In contrast to known CO2 fixation methods, this process proceeds under extremely mild conditions.

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