Department of Applied Chemistry, Graduate School of Engineering Osaka University MINAKATA Lab. Synthetic Organic Chemistry Research Group

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論文 Publication List at MINAKATA Lab.

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“C–H Oxygenation at Tertiary Carbon Centers Using Iodine Oxidant”
Kensuke Kiyokawa*, Ryo Ito, Kenta Takemoto, and Satoshi Minakata*
Chem. Commun. , Advance Article DOI:10.1039/C8CC03735C

Abstract: An oxidation system in which iodic acid (HIO3) is used as an oxidant in the presence of N-hydroxyphthalimide (NHPI) permitted the selective hydroxylation of tertiary C–H bonds and the lactonization of carboxylic acids containing a tertiary carbon center. These reactions are operationally simple and proceed under metal-free conditions using commercially available reagents, thus offering an ideal tool for the efficient oxidation of C–H bonds at tertiary carbon centers.

"Conformationally-Flexible and Moderately Electron-Donating Units-Installed Donor-Acceptor-Donor Triad Enabling Multicolor-Changing Mechanochromic Luminescence, Thermally Activated Delayed Fluorescence, and Room- Temperature Phosphorescence"
Youhie Takeda*, Takahito Kaihara, Masato Okazaki, Heather Higginbotham, Przemyslaw Data*, Norimitsu Tohnai, and Satoshi Minakata
Chem. Commun. 2018, 54, 6847–6850. DOI:10.1039/C8CC02365D

*Open-access Article!
*Invited Article as a part of the themed collection "Emerging Investigators Issue 2018"!
*Prof. Takeda was selected as an Emerging Investigator 2018! (link to Profile: Contbitutors to the Emerging Investigators Issue 2018)

Abstract: A novel twisted donor–acceptor–donor (D–A–D) π-conjugated compound that contains flexible and moderately-electron-donating units has been designed and synthesized. It exhibited not only multi-color-changing mechanochromic luminescence and thermally activated delayed fluorescence, but also, unexpectedly, room-temperature phosphorescence in a host layer.

"Hypervalent Iodine(III)-Mediated Decarboxylative Acetoxylation at Tertiary and Benzylic Carbon Centers"
Kensuke Kiyokawa*, Daichi Okumatsu, and Satoshi Minakata*
Beilstein J. Org. Chem. 2018, 14, 1046–1050. DOI:10.3762/bjoc.14.92

*Open-access Article!
*This article is part of the Thematic Series "Hypervalent iodine chemistry in organic synthesis"!

Abstract: The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)2 and I2 in a CH2Cl2/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditions. The resulting acetates were readily converted into the corresponding alcohols by hydrolysis.

"FRET-Mediated Near Infrared Whispering Gallery Modes: Studies on the Relevance of Intracavity Energy Transfer with Q-Factor"
Osamu Oki, Soh Kushida, Annabel Mikosch, Kota Hatanaka, Youhei Takeda, Satoshi Minakata, Junpei Kuwabara, Takaki Kanbara, Thang Duy Dao, Satoshi Ishii, Tadaaki Nagao, Alexader Kuehne, Felix Deschler, Rchard Friend, and Yohei Yamamoto*
Mater. Chem. Front. 2018, 2, 270–274. DOI:10.1039/C7QM00498B

*Invited Article as a part of the themed collection "Pi conjugated system bricolage (figuration) toward functional organic molecular systemms"!

Abstract: Near infrared (NIR) optical microsphere resonators are prepared by coassembly of energy-donating and accepting conjugated polymers. In the microspheres, fluorescence resonance energy transfer occurs, leading to sharp and periodic photoluminescence from whispering gallery modes in the NIR region with Q-factors as high as 600.

"Recent Advances in the Synthesis of β-Ketonitriles"
Kensuke Kiyokawa*, Takaya Nagata, and Satoshi Minakata*
Synthesis 2018, 50, 485–498. DOI:10.1055/s-0036-1589128

*Short Review!

Abstract: β-Ketonitriles are an important class of compounds in the field of organic and medicinal chemistry. Over the past decades, numerous efforts have been devoted to the development of new and efficient methodologies for the synthesis of these derivatives, and a number of efficient methods to accomplish this have been developed in recent years. In this context, this short review highlights recent advances in the synthesis of β-ketonitriles.

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