Lewis Acid-mediated Carbon-Fluorine Bond Transformation: Substitution of Fluorine and Insertion into a Carbon-Fluorine Bond
Yoshihiro Nishimoto and Makoto Yasuda J. Synth. Org. Chem., Jpn.2022, 80, 1000-1010. [Link]
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総説
Synthesis of Cage-Shaped Borates Bearing Pyrenylmethyl Groups: Efficient Lewis Acid Catalyst for Photoactivated Glycosylations Driven by Intramolecular Excimer Formation
Yuya Tsutsui, Daiki Tanaka, Yoshiyuki Manabe, Yuka Ikinaga, Kumpei Yano, Koichi Fukase, Akihito Konishi, and Makoto Yasuda Chem. Eur. J.2022, 28, e202202284. [Link]
Lewis Acid-Catalyzed Diastereoselective C–C Bond Insertion of Diazo Esters into Secondary Benzylic Halides for the Synthesis of α,β-Diaryl-β-haloesters
Fei Wang, Yoshihiro Nishimoto, and Makoto Yasuda Angew. Chem. Int. Ed.2022, 61, e202204462. [Link]
anti-Selective Borylstannylation of Alkynes with (o-Phenylenediaminato)borylstannanes by a Radical Mechanism
Kensuke Suzuki, Naoki Sugihara, Yoshihiro Nishimoto, and Makoto Yasuda Angew. Chem. Int. Ed.2022, 61, e202201883. [Link]
Indium-Catalyzed Formal Carbon–Halogen Bond Insertion: Synthesis of α-Halo-α,α-disubstituted Esters from Benzylic Halides and Diazo Esters
Fei Wang, Yoshihiro Nishimoto, and Makoto Yasuda Org. Lett.2022, 24, 1706–1710. [Link]
Bis-periazulene (Cyclohepta[def]fluorene) as a Nonalternant Isomer of Pyrene: Synthesis and Characterization of Its Triaryl Derivatives
Koki Horii, Ryohei Kishi, Masayoshi Nakano, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Akihito Konishi, and Makoto Yasuda J. Am. Chem. Soc.2022, 144, 3370–3375. [Link]
C(sp3)‒F Bond Transformation of Perfluoroalkyl Compounds Mediated by Visible-Light Photocatalysis: Spin-Center Shift and Radical/Polar Crossover Process via Anionic Intermediates
Yoshihiro Nishimoto, Naoki Sugihara, and Makoto Yasuda Synthesis 2022, 54, 2765-2777. [Link]
Short Review
Synthesis and Characterization of Dinaphtho[2,1-a:2,3-f]pentalene: A Stable Antiaromatic/Quinoidal Hydrocarbon Showing Appropriate Carrier Mobility in the Amorphous Layer
Koki Horii, Akira Nogata, Yusuke Mizuno, Haruna Iwasa, Mitsuharu Suzuki, Ken-ichi Nakayama, Akihito Konishi, and Makoto Yasuda Chem. Lett. 2022, 51, 325–329. [Link]
