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1) Ikuma, N.; Sumioka, S.; Asahara, H. Oshima, T. “Regioselective
electrophilic addition vs epoxidation of mCPBA towards anti-Bredt olefin of
fulleroid”, Tetrahedron
Lett., in press. (doi:
10.1016/j.tetlet.2012.05.007).
2) Oshima, T.; Mikie, T.; Ikuma, N.; Yakuma, H. “First
Kinetic Evidence for the CH/p
and p/p Solute-Solvent Interaction of C60
in Diels-Alder Reaction with Cyclohexadiene”, Org.
Biomol. Chem., 10, 1730-1734 (2012).
3) Saotome, T.; Kokubo, K.; Shirakawa, S.; Oshima, T.;
Hahn, H. T. “Polymer nanocomposites reinforced with C60 fullerene:
effect of hydroxylation”, Journal of Composite Materials, 45,
2595–2601 (2011).
4) Takaya, Y.; Kishida, H.; Hayashi, T.; Michihata,
M.; Kokubo, K. “Chemical mechanical polishing of patterned copper wafer surface
using water-soluble fullerenol slurry”, CIRP
Annals - Manufacturing Technology, 60, 567–570 (2011).
5) Ikuma, N; Susami, Y.; Oshima, T. “Notably Enhanced
Reactivity of the Fulleroid anti-Bredt Double Bond in Diels–Alder
Reactions”, Eur.
J. Org. Chem., 6452-6458 (2011).
6) Mikie, T.; Asahara, H.; Nagao, K.; Ikuma, N.; Kokubo,
K.; Oshima, T. “Thermal [2 + 2] Cycloaddition of Morpholinoenamines with C60
via a Single Electron Transfer”, Org.Lett., 13,
4244-4247 (2011).
7) Kokubo, K; Shirakawa, S; Kobayashi, N; Aoshima, H; Oshima, T. “Facile and Scalable Synthesis of a Highly Hydroxylated Water-Soluble Fullerenol as a Single Nanoparticle”, Nano Res. 4, 204-215 (2011).
8) Saitoh, Y.; Miyanishi, A.; Mizuno, H.; Kato, S.; Aoshima, H.; Kokubo, K.; Miwa, N. J. Photochem. Photobio. B, 102, 69-76 (2011).
9) Saitoh, Y.; Xiao, L.; Mizuno, H.; Kato, S.; Aoshima, H.; Taira, H.; Kokubo, K.; Miwa, N.” Novel Polyhydroxylated Fullerene Suppresses Intracellular Oxidative Stress Together with Repression of Intracellular Lipid Accumulation during the Differentiation of OP9 Preadipocytes into Adipocytes”, Free Radic. Res., 44, 1072-1081 (2010).
10) Kokubo, K; Arastoo, R. S.; Oshima, T; Wang, C. C.; Gao, Y.; Wang, H. L.; Geng, H.; Chiang, L. Y. “Synthesis and Regiochemistry of [60]Fullerenyl 2-Methylmalonate Bisadducts and their Facile Electron-Accepting Properties”, J. Org. Chem. 75, 4574-4583. (2010).
11) Ikuma, N; Susami, Y; Oshima, T. “Kinetics and Regioselectivity in Diels–Alder Reaction of Fulleroids vs Methanofullerene and C60”, Org. Biomol. Chem. 8, 1394-1398. (2010).
12) Asahara, H.; Saito, K.; Ikuma, N.; Oshima, T. “Kinetic Evidence for Dihapto (η2) π-Aryl Participation in Acid-Catalyzed Ring Opening of Diarylhomobenzoquinone Epoxides.” J. Org. Chem. 75 , 733-740 (2010).
13) Kokubo, K.; Harada, K.; Mochizuki, E.; Oshima, T. “A New Approach to Benzofuran Synthesis: Lewis Acid Mediated Cycloaddition of Benzoquinones with Stilbene Oxides” Tetrahedron Lett. 51 (6) 955-958 (2010).
14) Kokubo, K.; Thota, S.; Wang, H. L.; Chiang, L. Y. “Structural Analysis of Novel [60]Fullerene Bisadduct Regioisomers by DFT Calculation” J. Macromol. Sci. A. 46 (12) 1176-1181 (2009).
15) Thota, S.; Kokubo, K.; Tan, L.S.; Chiang, L. Y. “Synthesis of Highly Luminescent Tris-Fluorenyl Chromophores as Intermediates of Potential Nonlinear Photonic Materials.” J. Macromol. Sci. A. 46 (12) 1165-1171 (2009).
16) 青島央江、都賀谷京子、後藤忠示、伊藤雅之、小久保研、山名修一、大島巧、”フラーレン類の抗酸化能評価および汎用化粧品成分の光分解抑制効果” 日本香粧品学会誌 33 (3) 149-154 (2009).
17) Takaya, Y.; Tachika, H.; Hayashi, T.; Kokubo, K.; Suzuki, K. “Performance of Water-soluble Fullerenol as Novel Functional Molecular Abrasive Grain for Polishing Nanosurfaces.” CIRP Annals - Manufacturing Technology 58 (1) 495–498 (2009)
18) Matsubayashi, K.; Kokubo, K.; Tategaki, H.; Kawahama, S.; Oshima, T. “One-step Synthesis of Water-soluble Fullerenols Bearing Nitrogen-containing Substituents.” Fullerenes Nanotubes And Carbon Nanostructures 17 (4): 440-456 (2009).
19) Aoshima, H.; Kokubo, K.; Shirakawa, S.; Ito, M.; Yamana, S.; Oshima, T. “Antimicrobial Activity of Fullerenes and Their Hydroxylated Derivatives.” Biocontrol Science, 14 (2): 69-72 (2009).
20) 田近英之、高谷裕浩、林照剛、田名田祐樹、小久保研、鈴木恵友、”水酸化フラーレンスラリーを用いたCu-CMP加工法に関する研究 –研磨特性の検証–” 精密工学会誌 75 (4) 489-495 (2009).（精密工学会沼田記念論文賞受賞）
21) Matsubayashi, K.; Goto, T.; Togaya, K.; Kokubo, K.; Oshima, T. “Effects of pin-up oxygen on [60]Fullerene for enhanced antioxidant activity.” Nanoscale Research Letters 3 (7): 237-241 (2008).
22) Kokubo, K.; Tochika, S.; Kato, M.; Sol, Y.; Oshima, T. “AlCl3-catalyzed tandem acetylation of hydroarylated [60]fullerenes.” Org. Lett. 10 (15): 3335-3338 (2008).
23) Oshima, T.; Asahara, H.; Kubo, E.; Miyamoto, S.; Togaya, K. “Coformational effects in acid-mediated ring opening of epoxides: A prominent role of the oxirane Walsh orbital.” Org. Lett. 10 (12): 2413-2416 (2008).
24) Oshima, T.; Asahara, H.; Koizumi, T.; Miyamoto, S. “Mechanistic evidence for remote pi-aryl participation in acid-catalyzed ring opening of homobenzoquinone epoxides.” Chem. commun. 44 (15): 1804-1806 (2008).
25) Kokubo, K.; Matsubayashi, K.; Tategaki, H.; Takada, H.; Oshima, T. “Facile synthesis of highly water-soluble fullerenes more than half-covered by hydroxyl groups.” ACS NANO 2 (2): 327-333 (2008).
26) Kitamura, H.; Oshima, T. “Structural effects on thermal rearrangement of fulleroids to methanofullerenes. The prominent role of cyclopropyl vs aryl substituent.” Org. Lett. 10 (2): 293-296 (2008).
27) Kitamura, H.; Kokubo, K.; Oshima, T. “Stereoelectronic effects in diastereloselective formation of fulleroids.” Org. Lett. 9 (20): 4045-4048 (2007).
28) Asahara, H.; Kubo, E.; Togaya, K.; Koizumi, T.; Mochizuki, E.; Oshima, T. “Acid-catalyzed rearrangement of aryl-substituted homobenzoquinone epoxides.” Org. Lett. 9 (17): 3421-3424 (2007).
29) Takada, H.; Kokubo, K.; Matsubayashi, K.; Oshima, T. “Antioxidant activity of supramolecular water-soluble fullerenes evaluated by beta-carotene bleaching assay.” Bioscience Biotechnology And Biochemistry 70 (12): 3088-3093 (2006).
30) Asahara, H.; Mochizuki, E.; Oshima, T. “Conformational analysis in the reversible intramolecular [2+2] photocycloaddition of diphenylbicyclo[4.2.0]oct-3-ene-2,5-diones.” Tetrahedron Lett. 47 (45): 7881-7884 (2006).
31) Hamaguchi, M.; Tomida, N.; Iyama, Y.; Oshima, T. “Generation of acyloxyketenes from unstable mesoionic 1,3-dioxolium-4-olates and their reaction with ketenophiles to give [2+2] cycloadducts.” J. Org. Chem. 71 (14): 5162-5170 (2006).
32) Kokubo, K.; Kitasaka, K.; Oshima, T. “Supramolecular triplet photosensitizer. Effects of the cation binding mode on E-Z isomerization of 1,2-dichloroethylene.” Org. Lett. 8 (8): 1597-1600 (2006).
33) Oshima, T.; Kitamura, H.; Higashi, T.; Kokubo, K.; Seike, N. “Kinetic substituent and solvent effects in 1,3-dipolar cycloaddition of diphenyldiazomethanes with fullerenes C-60 and C-70: A comparison with the addition to TCNE, DDQ, and chloranil.” J. Org. Chem. 71 (8): 2995-3000 (2006).
34) Asahara, H.; Koizumi, T.; Mochizuki, E.; Oshima, T. “Two conformers of 10,11-dihydro-5H-dibenzo[a,d]cycloheptene spiro-linked with homobenzoquinone epoxide.” Acta. Cryst. C. 62: O136-O138, Part 3. (2006).
35) Hamaguchi, M.; Iyama, Y.; Mochizuki, E.; Oshima, T. “First isolation and characterization of 1,2-oxaphosphetanes with three phenyl groups at the phosphorus atom in typical Wittig reaction using cyclopropylidenetriphenylphosphorane.” Tetrahedron Lett. 46 (51): 8949-8952 (2005).
36) Koizumi, T.; Harada, K.; Asahara, H.; Mochizuki, E.; Kokubo, K.; Oshima, T. “Acid-catalyzed transannular cyclization of 3aH-cyclopentene[8]annulene-1,4-(5H,9aH)-diones and some proposed mechanisms.” J. Org. Chem. 70 (21): 8364-8371 (2005).
37) Kokubo, K.; Koizumi, T.; Harada, K.; Mochizuki, E.; Oshima, T. “Site selectivity switch in lewis acid catalysis. Mechanism and kinetic simulation of skeletal rearrangement of cyclobutene-fused homoquinones.” J. Org. Chem. 70 (19): 7776-7779 (2005).
38) Hamaguchi, M.; Tomida, N.; Mochizuki, E.; Oshima, T. “Reaction of electron deficient N=N bonds with acyloxyketenes and mesoionic 1,3-dioxolium-4-olates: fast equilibrium between acyloxyketenes and mesoionic 1,3-dioxolium-4-olates.” Tetrahedron Lett. 46 (8): 1259-1262 (2005).
39) Koizumi, T.; Harada, K.; Mochizuki, E.; Kokubo, K.; Oshima, T. “Kinetic evidence for remote pi-aryl participation in the BF3-catalyzed rearrangement of [2+2] photocycloadducts of diarylhomobenzoquinones with diphenylacetylene.” Org. Lett. 6 (22): 4081-4084 (2004).
40) Koizumi, T.; Mochizuki, E.; Kokubo, K.; Oshima, T. “Mechanism of novel consecutive rearrangements of cyclobutene-fused diphenylhomobenzoquinones catalyzed by Lewis acids.” J. Org. Chem. 69 (14): 4577-4585 (2004).
1)
Kokubo, K., “Water-Soluble Single-Nano Carbon
Particles: Fullerenol and Its Derivatives”, The
Delivery of Nanoparticles, edited by Abbass A. Hashim, InTech, Croatia, Chap.
15, pp317-332 (2012)
2)
小久保研 他、「大学を変えた人間力PROJECT“C”-教職協働への挑戦」、大阪大学出版会(2011)
3)
小久保研 他、「有機分散系の分散・凝集技術」、シーエムシー出版 (2008)
4)
小久保研、大島巧、林照剛、高谷裕浩、「最新CMP技術と周辺部材」、技術情報協会 (2008)
5)
大島巧、「クリックケミストリーと1,3-双極子付加反応」、化学と工業、60, 981-983 (2007)
6)
小久保研、「10億分の1にかける情熱」、生産と技術、59, 35-37 (2007)
7) 水野一彦、吉田潤一、大島 巧、太田哲男、瀬恒潤一郎、勝村成雄、垣内喜代三、石井康敬、「役にたつ化学シリーズ５」、朝倉書店 (2004)
8) 大島巧 他、「化学序説 第四版」、学術図書出版社 (2004)
1) 林寛幸、川上公徳、橋口昌彦、小久保研、伊熊直彦、柏原宮人、「フラーレン誘導体並びにその溶液およびその膜」、特願2011-026156、平成23年2月9日
2)
小久保研、加藤万依、田中克知、矢野智美、「フラーレン誘導体溶液、フラーレン誘導体膜及びフラーレン誘導体」、特願2008-143844
3) 小久保研、白川翔吾、大島巧、松林賢司、青島央江、「相間移動触媒およびポリ水酸化フラーレンの製造方法」、特願2007-031090
4) Takashi Miyoshi, Yasuhiro Takaya, Ken Kokubo, Kenji Matsubayashi, Takumi Oshima, “Polishing slurry for CMP processess of semiconductor integrated circuit interconnections”, WO2007-020939.
5) Takumi Oshima, Ken Kokubo, Koh Kidena, Nobuhiko Miwa, Kenji Matsubayashi, Hiroya Takada, “Water-soluble fullerene, process for producing the same, antioxidant composition and external composition”, WO2006-028297.
6) 大島巧、小久保研、立垣裕史、松林賢司、高田弘弥、「水酸化フラーレンとその製造方法並びに抗酸化組成物と外用組成物」、特開2007-176899、特願2005-380036
7) 三好 隆志、高谷 裕浩、小久保 研、松林 賢司、大島 巧、「研磨スラリー」、特願2005-263163
8) 小久保 研、匡 春香、東 帝治郎、大島 巧、吉田 五兵衛、松林 賢司、「フラーレン化ポリマースルホン酸からなるプロトン伝導体とその製造方法」、特開2007-12384、特願2005-190366
9) 大島巧，小久保研，貴傳名甲，三輪信比古，松林賢司，高田弘弥、「水溶性フラーレンとその製造方法並びに抗酸化組成物と外用組成物」、特願2004-264664
10) 東帝治郎，小久保研，大島巧、「プロトン伝導体」、特開2005-251505、特願2004-58692