Department of Applied Chemistry, Faculty of Engineering. Osaka University The CHATANI Group

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Publications

2018
  • Nickel-Catalyzed Reductive Cleavage of Carbon-Oxygen Bonds in Anisole Derivatives Using Diisopropylaminoborane
    T. Igarashi, A. Haito, N. Chatani, and M. Tobisu
    ACS Catal., in press.
  • Rhodium(I)-Catalyzed C8-Alkylation of 1-Naphthylamide Derivatives with Alkenes through a Bidentate Picolinamide Chelation System
    S. Rej and N. Chatani
    ACS Catal., 8(7), 6699-6706 (2018)
  • Rhodium(I)-Catalyzed C8-Alkylation of 1-Naphthylamide Derivatives with Alkenes through a Bidentate Picolinamide Chelation System
    S. Rej and N. Chatani
    ACS Catal., in press.
  • Ru3(CO)12-Catalyzed Carbonylation of C-H Bonds by Triazole Directed C-H Activation
    A. Haito, M. Yamaguchi, and N. Chatani
    Asian J. Org. Chem., in press. (a special issue on C-H activation)
  • Rhodium-Catalyzed C-O Bond Alkynylation of Aryl Carbamates with Propargyl Alcohols
    K. Yasui, N. Chatani, and M. Tobisu
    Org. Lett., 20 (7) , 2108-2111 (2018)
  • Cobalt(II)-Catalyzed Acyloxylation of C-H Bonds in Aromatic Amides with Carboxylic Acids
    R. Ueno, S. Natsui, and N. Chatani
    Org. Lett., 20 (4) , 1062-1065 (2018)
  • A Cationic Iridium-Catalyzed C(sp3)-H Silylation of 2-Alkyl-1,3-azoles at the ƒ¿-Position in the 2-Alkyl Group Leading to 2-(1-Silylalkyl)-1,3-azoles
    M. Hirano, Y. Fukumoto, N. Matsubara, and N. Chatani
    Chem. Lett., 47 (3), 385-388 (2018)
  • Cobalt(II)-Catalyzed Chelation-Assisted C-H Iodination of Aromatic Amides with I2
    Y. Kommagalla, K. Yamazaki, T. Yamaguchi, and N. Chatani
    Chem. Commun., 54 (11) , 1359-1362 (2018)
  • The Use of a Rhodium Catalyst/8-Aminoquinoline Directing Group in the C-H Alkylation of Aromatic Amides with Alkenes: Possible Generation of a Carbene Intermediate from an Alkene
    N. Chatani
    Bull. Chem. Soc. Jpn, 91 (2) , 211-222 (2018)
2017
2016
  • Nickel/N-Heterocyclic Carbene-Catalyzed Suzuki-Miyaura Type Cross-Coupling of Aryl Carbamates
    A. Ohtsuki, K. Yanagisawa, T. Furukawa, M. Tobisu and N. Chatani
    J. Org. Chem., 81 (19) , 9409-9414 (2016)
  • Nickel-catalyzed Ring-opening Cross-coupling of Cyclic Alkenyl Ethers with Arylboronic Esters via Carbon-Oxygen Bond Cleavage
    A. Ohtsuki, S. Sakurai, M. Tobisu and N. Chatani
    Chem. Lett., 45 (11), 1277-1279 (2016)
  • Palladium-Catalyzed Synthesis of 2,3-Disubstituted Benzothiophenes via the Annulation of Aryl Sulfides with Alkynes
    Y. Masuya, M. Tobisu and N. Chatani
    Org. Lett., 18 (17) , 4312-4315 (2016)
  • Cobalt-Catalyzed Chelation Assisted C-H Allylation of Aromatic Amides with Unactivated Olefins
    T. Yamaguchi, Y. Kommagalla, Y. Aihara, and N. Chatani
    Chem. Commun., 52 (66) , 10129-10132 (2016)
  • The Nickel-Catalyzed Reaction of C-H Bonds in Amides with I2:ortho-Iodination via the Cleavage of C(sp2)-H Bonds and Oxidative Cyclization to ƒÀ-Lactams via the Cleavage of C(sp3)-H Bonds
    Y. Aihara and N. Chatani
    ACS Catal., 6, 4323-4329 (2016)
  • Nickel-Catalyzed Alkylative Cross-Coupling of Anisoles with Grignard reagents via C-O Bond Activation
    M. Tobisu, T. Takahira, T. Morioka and N. Chatani
    J. Am. Chem. Soc., 138 (21) , 6711-6714 (2016)
  • Nickel-Catalyzed Borylation of Aryl and Benzyl 2-Pyridyl Ethers: A Method for Converting a Robust ortho-Directing Group
    M. Tobisu, J. Zhao, H. Kinuta, T. Furukawa, T. Igarashi and N. Chatani
    Adv. Synth. Catal., 358 (15) , 2417-2421 (2016)
  • Iridium/N-heterocyclic carbene-catalyzed C-H borylation of arenes by diisopropylaminoborane
    M. Tobisu, T. Igarashi and N. Chatani
    Beilstein J. Org. Chem., 12, 654-661 (2016)
  • Dicumyl Peroxide as a Methylating Reagent in the Ni-Catalyzed Methylation of ortho C-H Bonds in Aromatic Amides
    T. Kubo and N. Chatani
    Org. Lett., 18 (7) , 1698-1701 (2016)
  • Conversion of 3,3,3-Trisubstituted Prop-1-ynes with tert-Butylhydrazine into 3,3,3-Trisubstituted Propionitriles Catalyzed by TpRh(C2H4)2/P(2-fulyl)3
    Y. Fukumoto, Y. Tamura, Y. Iyori, and N. Chatani
    J. Org. Chem., 81 (8) , 3161-3167 (2016)
  • Palladium(II)-Catalyzed Synthesis of Dibenzothiophene Derivatives via the Cleavage of Carbon-Sulfur and Carbon-Hydrogen Bonds
    M. Tobisu, Y. Masuya, K. Baba, and N. Chatani
    Chem. Sci., 7 (4), 2587-2591 (2016)
  • Phenyltrimethylammonium Salts as a Methylation Reagent in the Ni-Catalyzed Methylation of C-H Bonds
    T. Uemura, M. Yamaguchi, and N. Chatani
    Angew. Chem. Int. Ed., 55 (9), 3162-3165 (2016)
  • Chelation-Assisted Nickel-Catalyzed Oxidative Annulation via Double C-H Activation/Alkyne Insertion Reaction
    L. C. Misal Castro, A. Obata, Y. Aihara, and N. Chatani
    Chem. Eur. J., 22 (4), 1362-1367 (2016)
  • Rhodium-Catalyzed Regioselective Addition of the ortho C-H Bonds in Aromatic Amides to C-C Double Bonds in ƒ¿,ƒÀ-Unsaturated ƒÁ-Lactones and Dihydrofurans
    K. Shibata and N. Chatani
    Chem. Sci., 7 (1), 240-245 (2016)
2015
2014
2013
  • Rhodium-Catalyzed Anti-Markovnikov Hydrohydrazination of Terminal Alkynes with N-Alkyl- and N,N-Dialkylhydrazines
    Y. Fukumoto, A. Ohmae, M. Hirano, N. Chatani
    Asian J. Org. Chem., 2 (12), 1036–1039 (2013)
  • Skeletal Reorganization of Enynes Catalyzed by a Ru(II)-Ru(III) Mixed Valence Complex Under an Atmosphere of O2 or CO
    T. Nakae, T. Yasunaga, M. Kamiya, Y. Fukumoto, and N. Chatani
    Chem. Lett., 42 (12), 1565-1567 (2013)
  • Palladium-Catalyzed Direct Synthesis of Phosphole Derivatives from Triarylphosphines via Cleavage of Carbon-Hydrogen and Carbon-Phosphorus Bonds
    K. Baba, M. Tobisu, and N. Chatani
    Angew. Chem. Int. Ed., 52 (45), 11892–11895 (2013).
  • Catalytic Functionalization of C(sp2)-H and C(sp3)-H Bonds Using Bidentate Directing Groups
    G. Rouquet and N. Chatani
    Angew. Chem. Int. Ed., 52 (45), 11726–11743 (2013).
  • Visible Light-Mediated Direct Arylation of Arenes and Heteroarenes Using Diaryliodonium Salts in the Presence and Absence of a Photocatalyst
    M. Tobisu, T. Furukawa, and N. Chatani
    Chem. Lett., 42 (19) 1203-1205 (2013).
  • Ruthenium-Catalyzed Cyclocarbonylation of Aliphatic Amides through
    the Regioselective Activation of Unactivated C(sp3)-H Bonds
    N. Hasegawa, K. Shibata, V. Charra, S. Inoue, Y. Fukumoto, and N. Chatani
    Tetrahedron, 69, 4466-4472(2013).
  • Nickel-Catalyzed Direct Alkylation of CH Bonds in Benzamides and
    Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation
    Assistance
    Y. Aihara and N. Chatani
    J. Am. Chem. Soc., 135 (14), 5308–5311(2013).
  • Ruthenium-Catalyzed Ortho C-H Bond Alkylation of Aromatic Amides with
    α,β-Unsaturated Ketones via a Bidentate-Chelation Assistance
    G. Rouquet and N. Chatani
    Chem. Sci., 4 (5), 2201-2208 (2013).
  • Synthesis of Six-membered Silacycles by Intramolecular Nucleophilic Substitution at Silicon Involving the Cleavage of CarbonSilicon Bonds
    M. Onoe, T. Morioka, M. Tobisu, and N. Chatani
    Chem. Lett., 42 (3), 238-240 (2013).
  • Ruthenium-Catalyzed Direct Arylation of C-H Bonds in Aromatic Amides
    containing a Bidentate Directing Group: Significant Electronic Effects on Arylation
    Y. Aihara and N. Chatani
    Chem. Sci., 4 (2), 664-670 (2013).
2012
2011
2010
2009
  • Rh(II)-Catalyzed Skeletal Reorganization of 1,6- and 1,7-Enynes through Electrophilic Activation of Alkynes
    K. Ota, S. I. Lee, J.-M. Tang, M. Takachi, H. Nakai, T. Morimoto, H. Sakurai, K. Kataoka, and N. Chatani
    J. Am. Chem. Soc., 131 (42), 15203-15211 (2009).
  • Nickel-Catalyzed Cross-Coupling Reaction of Alkenyl Methyl Ethers with Aryl Boronic Esters
    T. Shimasaki, Y. Konno, M. Tobisu, and N. Chatani
    Org. Lett., 11 (21), 4890-4892 (2009).
  • Synthesis of (E)-3-Alkylidene-1-pyrrolines by the Rhodium- Catalyzed Cyclization of Terminal Alkynes with Homopropargylic Amines
    Y. Fukumoto, T. Kawahara, Y. Kanazawa, and N. Chatani
    Adv. Synth. Catal., 305 (14-15), 2315-2318 (2009).
  • Nickel-Catalyzed Reaction of Arylzinc Reagents with N-Aromatic Heterocycles: A Straightforward Approach to C-H Bond Arylation of Electron-Deficient Heteroaromatic Compounds
    M. Tobisu, I. Hyodo, and N. Chatani
    J. Am. Chem. Soc., 131 (34), 12070-12071 (2009).
  • Palladium-Catalyzed Direct Alkynylation of C-H Bonds in Benzenes
    M. Tobisu, Y. Ano, and N. Chatani
    Org. Lett., 11 (15), 3250-3252 (2009).
  • Platinum and Ruthenium Chlorides-Catalyzed Cycloisomerization of 1-Alkyl-2-ethynylbenzenes: Interception of pi-Activated Alkynes with a Benzylic C-H Bond
    M. Tobisu, H. Nakai, and N. Chatani
    J. Org. Chem., 74 (15), 5471-5475 (2009).
  • Rhodium-Catalyzed Coupling of 2-Silylphenylboronic Acids with Alkynes Leading to Benzosiloles: Catalytic Cleavage of the Carbon-Silicon Bond in Trialkylsilyl Groups
    M. Tobisu, M. Onoe, Y. Kita, and N. Chatani
    J. Am. Chem. Soc., 131 (22), 7506-7507 (2009).
  • Ni(0)-catalyzed Direct Amination of Anisoles Involving the Cleavage of Carbon-Oxygen Bonds
    M. Tobisu, T. Shimasaki, and N. Chatani
    Chem. Lett., (38), 710-711 (2009).
  • Ruthenium-Catalyzed Carbonylation at ortho C-H Bonds in Aromatic Amides Leading to Phthalimides: C-H Bond Activation Utilizing a Bidentate System
    S. Inoue, H. Shiota, Y. Fukumoto, and N. Chatani
    J. Am. Chem. Soc., 131(20), 6898-6899 (2009).
  • Devising Boron Reagents for Orthogonal Functionalization via Consecutive Suzuki-Miyaura Cross-Couplings (Highlight)
    M. Tobisu and N. Chatani
    Angew. Chem., Int. Ed., 48(20), 3565-3568 (2009).
  • Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde
    T. Morimoto, K. Yamasaki, A. Hirano, K. Tsutumi, N. Kagawa, K. Kakiuchi, Y. Harada, Y. Fukumoto, N. Chatani, and T. Nishioka
    Org. Lett., 11(8), 1777-1780 (2009).
  • Rhodium-Catalyzed Reductive Cleavage of Carbon-Cyano Bonds with Hydrosilanes: A Catalytic Protocol for Removal of Cyano Groups
    M. Tobisu, R. Nakamura, Y. Kita, and N. Chatani
    J. Am. Chem. Soc., 131(9), 3174-3175 (2009).
  • Unique Effect of Coordination of an Alkene Moiety in Products on Ruthenium-Catalyzed Chemoselective C-H Alkenylation
    S. Ueno, T. Kochi, N. Chatani, and F. Kakiuchi
    Org. Lett., 11(4), 855-858 (2009).
  • Skeletal Reorganization of Enynes through Electrophilic Activation of Alkynes with Various Metal Catalysts: Double Cleavage of C-C Double Bond and Triple Bond
    S. I. Lee and N. Chatani
    Chem. Commun., (Feature Article), 371-384 (2009).
2008
2007
2006
2005
2004
  • Ruthenium-Catalyzed Functionalization of Aryl Carbon-Oxygen Bonds in Aromatic Ethers with Organoboron Compounds
    F. Kakiuchi, M. Usui, S. Ueno, N. Chatani, and S. Murai
    J. Am. Chem. Soc., 126(9), 2706-2707 (2004).
  • Ruthenium- and Rhodium-Catalyzed Direct Carbonylation of the Ortho C-H Bond in the Benzene Ring of N-Arylpyrazoles
    T. Asaumi, T. Matsuo, T. Fukuyama, Y. Ie, F. Kakiuchi, and N. Chatani
    J. Org. Chem., 69(13), 4433-4440 (2004).
  • Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and Decarbonylative Reduction of Esters with HCOONH4: A New Route to Acyl Transition Metal Complexes through the Cleavage of Acyl-Oxygen Bonds in Esters
    H. Tatamidani, K. Yokota, F. Kakiuchi, and N. Chatani
    J. Org. Chem., 69(17), 5615-5621 (2004).
  • A New Ketone Synthesis by Palladium-Catalyzed Cross-Coupling Reactions of Esters with Organoboron Compounds
    H. Tatamidani, F. Kakiuchi, and N, Chatani
    Org. Lett., 6(20), 3597-3599 (2004).
  • Ru3(CO)12-Catalyzed Silylation of Benzylic C-H Bonds in Arylpyridines and Arylpyrazoles with Hydrosilanes via C-H Bond Cleavage
    F. Kakiuchi, K. Tsuchiya, M. Matsumoto, E. Mizushima, and N. Chatani
    J. Am. Chem. Soc., 126(40), 12792-12793 (2004).
  • Efficient Synthesis of 1-Adamantanecarboxaldehyde by the GaCl3-Mediated Carbonylation of Adamantane under Mild Reaction Conditions
    M. Oshita and N. Chatani
    Org. Lett., 6(23), 4323-4325 (2004).
  • Skeletal Reorganization of Enynes into 1-Vinylcycloalkenes in Ionic Liquids
    Y. Miyanohana, H. Inoue, and N. Chatani
    J. Org. Chem., 69(24), 8541-8543 (2004).
2003
  • Ruthenium-Catalyzed Carbonylative Cycloaddition of ƒ¿-Keto Lactones with Alkenes or Alkynes: The Participation of an Ester-Carbonyl group in Cycloaddition Reactions as the Two-Atom Assembling Unit
    N. Chatani, K. Amako, M. Tobisu, T. Asaumi, Y. Fukumoto, and S. Murai
    J. Org. Chem., 68(4), 1591-1593 (2003).
  • A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Arylboronates: A New Method for the Arylation of Aromatic Compounds via C-H Bond Cleavage
    F. Kakiuchi, S. Kan, K. Igi, N. Chatani, and S. Murai
    J. Am. Chem. Soc., 125(7), 1698-1699 (2003).
  • Palladium-Catalyzed Carbonylation of 2-(Propargyl)allyl Phosphates Leading to Highly Unsaturated ƒÁ-Lactones
    A. Kamitani, N. Chatani, and S. Murai
    Angew. Chem. Int. Ed., 42(12), 1397-1399 (2003).
  • A GaCl3-Catalyzed [4+1] Cycloaddition of ƒ¿,ƒÀ-Unsaturated Carbonyl Compounds and Isocyanides Leading to Unsaturated g-Lactone Derivatives
    N. Chatani, M. Oshita, M. Tobisu, Y. Ishii, and S. Murai
    J. Am. Chem. Soc., 125(26), 7812-7813 (2003).
  • Ruthenium-Catalyzed C-H/CO/Olefin Coupling Reaction of N-Arylpyrazoles.
    Extraordinary Reactivity of N-Arylpyrazoles toward Carbonylation at C-H Bonds
    T. Asaumi, N. Chatani, T. Matsuo, F. Kakiuchi, and S. Murai
    J. Org. Chem., 68(19), 7538-7540 (2003).
  • Catalytic Methods for C-H Bond Functionalization: Application in Organic Synthesis
    F. Kakiuchi and N. Chatani
    Adv. Synth. Catal., 345(9-10), 1077-1101 (2003).
  • A Chelation- Assisted Hydroesterification of Alkenes Catalyzed by Rhodium Complex
    K. Yokota, H. Tatamidani, Y. Fukumoto, and N. Chatani
    Org. Lett., 5(23), 4329-4331 (2003).
  • The Ruthenium-Catalyzed Silylation of Aromatic C-H Bonds with Triethylsilane
    F. Kakiuchi, M. Matsumoto, K. Tsuchiya, K. Igi, T. Hayamizu, N. Chatani, and S. Murai
    J. Organomet. Chem., 686(1/2), 133-144 (2003).
2002
  • Cycloisomerization of ƒÖ-Aryl-1-Alkynes: GaCl3 as a Highly Electrophilic Catalyst for Alkyne Activation
    H. Inoue, N. Chatani, and S. Murai
    J. Org. Chem., 67(4), 1414-1417 (2002).
  • A New Chelation-Assistance Mode for a Ruthenium-Catalyzed Silylation at the C-H Bond in Aromatic Ring with Hydrosilanes
    F. Kakiuchi, K. Igi, M. Matsumoto, T. Hayamizu, N. Chatani, and S. Murai
    Chem. Lett., (3), 396-397 (2002).
  • Ruthenium-Catalyzed Addition of Olefinic C-H Bonds in Conjugate Enones to Acetylenes to Give Conjugate Dienones
    F. Kakiuchi, T. Uetsuhara, Y. Tanaka, N. Chatani, and S. Murai
    J. Mol. Catal. A., 182-183, 511-514 (2002).
  • Ir4(CO)12-Catalyzed Coupling Reaction of Imidazoles with Aldehydes in the Presence of a Hydrosilane to Give 2-Substituted Imidazoles
    Y. Fukumoto, K. Sawada, M. Hagihara, N. Chatani, and S. Murai
    Angew. Chem. Int. Ed., 41(15), 2779-2781 (2002).
  • Skeletal Reorganization of Enynes to 1-Vinylcycloalkenes Catalyzed by GaCl3
    N. Chatani, H. Inoue, T. Kotsuma, and S. Murai
    J. Am. Chem. Soc., 124(35), 10294-10295 (2002).
  • Reaction of Terminal Alkynes with Hydrazines to Give Nitriles Catalyzed by TpRuCl(PPh3)2: Novel Catalytic Transformation Involving a Vinylidene Ruthenium Intermediate
    Y. Fukumoto, T. Dohi, H. Masaoka, N. Chatani, and S. Murai
    Organometallics, 21(19), 3845-3847 (2002).
  • Ruthenium-Catalyzed Reaction of ƒ¿,ƒÀ-Unsaturated Imines with Carbon Monoxide and Alkenes Leading to ƒÀ,ƒÁ-Unsaturated ƒÁ-Butyrolactams: Involvement of Direct Carbonylation of Olefinic C-H Bonds as a Key Step
    N. Chatani, A. Kamitani, and S. Murai
    J. Org. Chem., 67(20), 7014-7018 (2002).
  • Ru3(CO)12-Catalyzed C-H/CO/Olefin Coupling of N-Pyridylindolines. Direct Carbonylation at a C-H Bond ƒÂ to the Pyridine Nitrogen
    N. Chatani, S. Yorimitsu, T. Asaumi, F. Kakiuchi, and S. Murai
    J. Org. Chem., 67(21), 7557-7560 (2002).
  • Catalytic C-H/Olefin Coupling
    F. Kakiuchi and S. Murai
    Acc. Chem. Res., 35(10), 826-834 (2002).
2001
  • Ynolate Chemistry. Reaction of a Silylynolate with Aziridines Leading to ƒÁ-Lactams
    K. Iwamoto, M. Kojima, N. Chatani, and S. Murai
    J. Org. Chem., 66(1), 169-174 (2001).
  • The Ruthenium-Catalyzed Addition of ƒÀ-C-H Bonds in Aldehydes to Olefins
    F. Kakiuchi, T. Sato, K. Igi, N. Chatani, and S. Murai
    Chem. Lett., (5), 386-387 (2001).
  • Ruthenium-Catalyzed Dehydrogenative Silylation of Aryloxazolines with Hydrosilanes via C-H Bond Cleavage
    F. Kakiuchi, K. Igi, M. Matsumoto, N. Chatani, and S. Murai
    Chem. Lett., (5), 422-423 (2001).
  • The Ruthenium-Catalyzed Reductive Decarboxylation of Esters: Catalytic Reactions Involving the Cleavage of Acyl-Oxygen Bonds of Esters
    N. Chatani, H. Tatamidani, Y. Ie, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 123(20), 4849-4850 (2001).
  • The Transition Metal-Catalyzed Addition of C-H Bonds in Aromatic Hydrazones to Olefins
    F. Kakiuchi, T. Tsujimoto, M. Sonoda, N. Chatani, and S. Murai
    Synlett (special issue), 948-951 (2001).
  • Iridium(I)-Catalyzed Cycloisomerization of Enynes
    N. Chatani, H. Inoue, T. Morimoto, T. Muto, and S. Murai
    J. Org. Chem., 66(12), 4433-4436 (2001).
  • Mechanistic Study of the Ru(H)2(CO)(PPh3)3-Catalyzed Addition of C-H Bonds in Aromatic Esters to Olefins
    F. Kakiuchi, H. Ohtaki, M. Sonoda, N. Chatani, and S. Murai
    Chem. Lett.,(9), 918-919 (2001).
  • Ru3(CO)12-Catalyzed Coupling Reaction of sp3 C-H Bonds Adjacent to a Nitrogen Atom in Alkylamines with Alkenes
    N. Chatani, T. Asaumi, S. Yorimitsu, T. Ikeda, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 123(44), 10935-10941 (2001).
  • Catalytic Carbonylation Reactions of Benyne Derivatives
    N. Chatani, A. Kamitani, M. Oshita, Y. Fukumoto, and S. Murai
    J. Am. Chem. Soc., 123(50), 12686-12687 (2001).
2000
  • The Co2(CO)8-Catalyzed Hydrosilylation of Oxygen-Containing Olefins: Silylmetalation as a Key Step
    N. Chatani, T. Kodama, Y. Kajikawa, H. Murakami, F. Kakiuchi, S. Ikeda, and S. Murai
    Chem. Lett., (1), 14-15 (2000).
  • Direct Carbonylation at a C-H Bond in the Benzene Ring of 2-Phenyloxazolines Catalyzed by Ru3(CO)12. Scope, Limitations, and Mechanistic Aspects
    Y. Ie, N. Chatani, T. Ogo, D. R. Marshall, T. Fukuyama, F. Kakiuchi, and S. Murai
    J. Org. Chem., 65(5), 1475-1488 (2000).
  • A Platinum Complex-Catalyzed Reaction of 3-Chloro-1,3-diene Monoepoxides with Carbon Nucleophiles Involving Nucleophilic Sybstitution at the Central Carbon Atom of the ƒÎ-Allyl Ligand in the Intermediate Complex. Dependency of Regioselectivity upon the Added Lewis Acids
    J. Kodota, N. Chatani, and S. Murai
    Tetrahedron, 56(15), 2231-2237 (2000).
  • The Ru3(CO)12-Catalyzed Intermolecular [2 + 2 + 1] Cyclocoupling of Imines, Alkenes or Alkynes, and Carbon Monoxide: A New Synthesis of Functionalized ƒÁ-Lactames
    N. Chatani, M. Tobisu, T. Asaumi, and S. Murai
    Synthesis, (7), 925-928 (2000).
  • Acylation of Five-Membered N-Heteroaromatic Compounds by Ruthenium Carbonyl- Catalyzed Direct Carbonylation at a C-H Bond
    N. Chatani, T. Fukuyama, H. Tatamidani, F. Kakiuchi, and S. Murai
    J. Org. Chem., 65(13), 4039-4047 (2000).
  • A New Synthetic Route to Heteroarylsilanes via Ruthenium-Catalyzed C-H/SiR3Coupling
    F. Kakiuchi, M. Matsumoto, M. Sonoda, T. Fukuyama, N. Chatani, S. Murai, N. Furukawa, and Y. Seki
    Chem. Lett., (7), 750-751 (2000).
  • Atropselective Alkylation of Biaryl Compounds by Means of Transition Metal-Catalyzed C-H/Olefin Coupling
    F. Kakiuchi, P. Le Gendre, A. Yamada, H. Ohtaki, and S. Murai
    Tetrahedron: Asymmetry, 11(13), 2647-2651 (2000).
  • A New Synthetic Route to Heteroarylsilanes via Ruthenium-Catalyzed C-H/SiR3 Coupling
    F. Kakiuchi, M. Matsumoto, M. Sonoda, T. Fukuyama, N. Chatani, S. Murai, N. Furukawa, and Y. Seki
    Chem. Lett., (7), 750-751 (2000).
  • Ru(II)- or Pt(II)-Catalyzed Cycloisomerization of ƒÖ-Aryl-1-alkynes. Generation of Carbocationic Species from Alkynes and Transition Metal Halides and Its Interception by an Aromatic Ring
    N. Chatani, H. Inoue, T. Ikeda, and S. Murai
    J. Org. Chem., 65(16), 4913-4918 (2000).
  • Reaction of o-Oxazolinylphenyllithium with Carbon Monoxide. Carbonylative Cyclization via an Aroyllthium Intermediate
    K. Iwamoto, N. Chatani, and S. Murai
    J. Org. Chem., 65(23), 7944-7948 (2000).
  • Ru3(CO)12-Catalyzed Intermolecular Cyclocoupling of Ketones, Alkenes or Alkynes, and Carbon Monoxide. [2 + 2 + 1] Cycloaddition Strategy for the Synthesis of Functionalized ƒÁ-Butyrolactones
    M. Tobisu, N. Chatani, T. Asaumi, K. Amako, Y. Ie, Y. Fukumoto, and S. Murai
    J. Am. Chem. Soc., 122(51), 12663-12674 (2000).
  • Carbonylation at sp3 C-H Bonds Adjacent to a Nitrogen Atom in Alkylamines Catalyzed by Rhodium Complexes
    N. Chatani, T. Asaumi, T. Ikeda, S. Yorimitsu, Y. Ishii, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 122(51), 12882-12883 (2000).
  • Carbonylative [5 + 1]Cycloaddition of Cyclopropyl Imines Catalyzed by Ruthenium Carbonyl Complex
    A. Kamitani, N. Chatani, T. Morimoto, and S. Murai
    J. Org. Chem., 65(26), 9230-9233 (2000).
1999
  • TRuthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins
    F. Kakiuchi, T. Sato, M. Yamauchi, N. Chatani, and S. Murai
    Chem. Lett., (1), 19-20 (1999).
  • The Carbonyllithium Chemistry. Intramolecular Conversion of the Acyllithium by the Utilization of Anionic 1,2-Stannyl Rearrangement
    K. Iwamoto, N. Chatani, and S. Murai
    J. Organomet. Chem., 574(1), 171-175 (1999).
  • The First Catalytic Carbonylative [4 + 1]Cycloaddition Using a 1,3-Conjugated System. A New Transformation of ƒ¿,ƒÀ-Unsaturated Imines to Unsaturated ƒÁ-Lactams Catalyzed by Ru3(CO)12
    T. Morimoto, N. Chatani, and S. Murai
    J. Am. Chem. Soc., 121(8), 1758-1759 (1999).
  • Silyl Group Transfer from Allylsilanes to Olefins Catalyzed by a Ruthenium(II) Complex
    F. Kakiuchi, A. Yamada, N. Chatani, S. Murai, N. Furukawa, and Y. Seki
    Organometallics, 18(10), 2033-2036 (1999).
  • Transition Metal-Catalyzed Dehydrogenative Germylation of Olefins with Hydrogermanes
    N. Furukawa, N. Kourogi, Y. Seki, F. Kakiuchi, and S. Murai
    Organometallics, 18(10), 3764-3767 (1999).
  • Ru3(CO)12-Catalyzed Reaction of Yne-Imines with Carbon Monoxide Leading to Bicyclic ƒ¿,ƒÀ-Unsaturated Lactams
    N. Chatani, T. Morimoto, A. Kamitani, Y. Fukumoto, and S. Murai
    J. Organomet. Chem., 579(1/2), 177-181 (1999).
  • Ruthenium Carbonyl-Catalyzed [2 + 2 + 1]Cycloaddition of Ketones, Olefins, and Carbon Monoxide Leading to Functionalized ƒÁ-Butyrolactones
    N. Chatani, M. Tobisu, T. Asaumi, Y. Fukumoto, and S. Murai
    J. Am. Chem. Soc., 121(30), 7160-7161 (1999).
  • Ru3(CO)12-Catalyzed Decarbonylative Cleavage of a C-C Bond in Alkyl Phenyl Ketones
    N. Chatani, Y. Ie, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 121(37), 8645-8646 (1999).
  • The Ruthenium-Catalyzed Addition of C-H Bonds in Aromatic Nitriles to Olefins
    F. Kakiuchi, T. Tsujimoto, M. Sonoda, N. Chatani, and S. Murai
    Chem. Lett., (10), 1083-1084 (1999).
1998
  • Transition Metal-Catalyzed Intramolecular Cyclization of 1,5- and 1,6-Dienes via Direct Cleavage and Addition of the Carbon-Hydrogen Bond
    N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai
    Bull. Chem. Soc. Jpn., 71(1), 285-298 (1998).
  • Rhodium-Catalyzed Si-F Exchange Reaction between Fluorobenzenes with a Disilane. Catalytic Reaction Involving Cleavage of C-F Bonds
    Y. Ishii, N. Chatani, S. Yorimitsu, and S. Murai
    Chem. Lett., (2), 157-158 (1998).
  • Ru3(CO)12-Catalyzed Cyclocarbonylation of Yne-aldehydes to Bicyclic ƒ¿,ƒÀ-Unsaturated ƒÁ-Butyrolactones
    N. Chatani, T. Morimoto, Y. Fukumoto, and S. Murai
    J. Am. Chem. Soc., 120(21), 5335-5336 (1998).
  • Ru3(CO)12- and Rh4(CO)12-Catalyzed Reactions of Pyridylolefins or N-(2-Pyridyl)enamines with CO and Olefins. Carbonylation at Olefinic C-H Bonds
    N. Chatani, Y. Ishii, Y. Ie, F. Kakiuchi, and S. Murai
    J. Org. Chem., 63(15), 5129-5136 (1998).
  • Ruthenium-Catalyzed Reactions of Acyclic ƒ¿,ƒÀ-Enones with Olefins and Their Reaction Mechanism
    T. Sato, F. Kakiuchi, N. Chatani, and S. Murai
    Chem. Lett., (9), 893-894 (1998).
  • Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed Cycloisomerization of Ene-ene-ynes. Interception of a Carbenoid Intermediate in Skeletal Reorganization of Enynes
    N. Chatani, K. Kataoka, S. Murai, N. Furukawa, and Y. Seki
    J. Am. Chem. Soc., 120(35), 9104-9105 (1998).
  • New Protocol for the Siteselective Alkylation and Vinylation of Aromatic Compounds. Catalyst-Specific Reactions
    F. Kakiuchi, T. Sato, T. Tsujimoto, M. Yamauchi, N. Chatani, and S. Murai
    Chem. Lett., (10), 1053-1054 (1998).
  • Ru3(CO)12-Catalyzed Siteselective Carbonylation Reactions at a C-H Bond in Aza-Heterocycles
    T. Fukuyama, N. Chatani, J. Tatsumi, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 120(44), 11522-11523 (1998).
1997
  • Catalytic Addition of C-H Bonds to Multiple Bonds
    S. Murai, N. Chatani, and F. Kakiuchi
    Pure & Appl. Chem., 69(3), 589-594 (1997).
  • Enantioselective Catalytic Ring Opening of Epoxides with Carboxylic Acids
    Eric N. Jacobsen, Fumitoshi Kakiuchi, Reed G. Konsler, Jay F. Larrow, and Makoto Tokunaga
    Tetrahedron Lett., 38(5), 773-776 (1997).
  • Ru3(CO)12-Catalyzed Reaction of Pyridylbenzenes with Carbon Monoxide and Olefins. Carbonylation at a C-H Bond in the Benzene Ring
    N. Chatani, Y. Ie, F. Kakiuchi, and S. Murai
    J. Org. Chem., 62(8), 2604-2610 (1997).
  • Asymmetric Intramolecular C-H/Olefin Coupling: Asymmetric Cyclization Reactions of 1,5-Dienes Catalyzed by Rhodium Complexes
    N. Fujii, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai
    Chem. Lett., (5), 425-426 (1997).
  • Reductive Oligomerization of Carbon Monoxide by Rhodium-Catalyzed Reaction with Hydrosilanes
    N. Chatani, M. Shinohara, S. Ikeda, and S. Murai
    J. Am. Chem. Soc., 119(18), 4303-4304 (1997).
  • Ru3(CO)12-Catalyzed Cyclocarbonylation of 1,6-Enynes
    T. Morimoto, N. Chatani, Y. Fukumoto, and S. Murai
    J. Org. Chem., 62(11), 3762-3765 (1997).
  • Catalytic Dimerization of Acrylonitrile
    Kohichi Kashiwagi, Ryoji Sugise, Toshihiro Shimakawa, Tunao Matuura, Masashi Shirai, Fumitoshi Kakiuchi, and Shinji Murai
    Organometallics, 16(11), 2233-2235 (1997).
  • Rhodium-Catalyzed Reaction of N-(2-Pyridyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring
    Y. Ishii, N. Chatani, F. Kakiuchi, and S. Murai
    Organometallics, 16(16), 3615-3622 (1997).
  • A New Synthetic Method for the Preparationof Indenones from Imines. Ru3(CO)12-Catalyzed Carbonylation at an ortho C-H Bond in the Aromatic Imines
    T. Fukuyama, N. Chatani, F. Kakiuchi, and S. Murai
    J. Org. Chem., 62(16), 5647-5650 (1997).
  • Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides via Catlytic Hydrolysis
    Makoto Tokunaga, Jay F. Larrow, Fumitosni Kakiuchi, and Eric N. Jacobsen
    Science, 277(5328), 936-938 (1997).
  • Rhodium-Catalyzed Reaction of N-Acylpiperazines with CO and Ethylene. Carbonylation at a C-H Bond Directed by an Amido Group
    Y. Ishii, N. Chatani, F. Kakiuchi, and S. Murai
    Tetrahedron Lett., 38(43), 7565-7568 (1997).
  • Ruthenium-Catalyzed Addition of Carbon-Hydrogen Bonds in Aromatic Ketones to Olefins. The Effect of Various Substituents at the Aromatic Ring
    M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai
    Bull. Chem. Soc. Jpn., 70(12), 3117-3128 (1997).
1996
  • Ru3(CO)12-Catalyzed Coupling of Heteroaromatic C-H/CO/ Olefins. Regioselective Acylation of the Imidazole Ring
    N. Chatani, T. Fukuyama, F. Kakiuchi, and S. Murai
    J. Am. Chem. Soc., 118(2), 493-494 (1996).
  • Ruthenium-Catalyzed Addition of Aromatic Esters at the ortho C-H Bonds to Olefins
    M. Sonoda, F. Kakiuchi, A. Kamatani, N. Chatani, and S. Murai
    Chem. Lett., (2), 109-110 (1996).
  • Ruthenium-Catalyzed Addition of Aromatic Imines at the ortho C-H Bonds to Olefins
    F. Kakiuchi, M. Yamauchi, N. Chatani, S. Murai
    Chem. Lett., (2), 111-112 (1996)
  • PtCl2-Catalyzed Conversion of 1,6- and 1,7-Enynes to 1-Vinylcycloalkenes. Anomalous Bond Connection in Skeletal Reorganization of Enynes
    N. Chatani, N. Furukawa, H. Sakurai, and S. Murai
    Organometallics, 15(3), 901-903 (1996).
  • HSiR3/CO as the Potent Reactant Combination in Developing New Transition-Metal-Catalyzed Reactions
    N. Chatani and S. Murai
    Synlett, (5), 414-424 (1996).
  • Ynolates from the Reaction of Lithiosilyldiazomethane with Carbon Monoxide. New Ketenylation Reactions
    H. Kai, K. Iwamoto, N. Chatani, and S. Murai
    J. Am. Chem. Soc., 118(32), 7634-7635 (1996).
  • Transition Metal Catalyzed Intramolecular C-H/Olefin Coupling
    N. Fujii, F. Kakiuchi, N. Chatani, and S. Murai
    Chem. Lett., (11), 939-940 (1996).
1995
  • Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins with the Aid of Ruthenium Complexes
    F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai
    Bull. Chem. Soc. Jpn., 68(1), 62-83 (1995)
  • Ring-Opening Silylformylation of Oxetanes Catalyzed by [RhCl(CO)2]2-amine
    Y. Fukumoto, S. Yamaguchi, N. Chatani, and S. Murai
    J. Organomet. Chem., 489(1/2), 215-219 (1995).
  • Pd-Catalyzed Coupling Reaction of Acetylenes, Iodotrimethylsilane, and Organozinc Reagents for the Stereoselective Synthesis of Vinylsilanes
    N. Chatani, N. Amishiro, T. Morii, T. Yamashita, and S. Murai
    J. Org. Chem., 60(6), 1834-1840 (1995).
  • Catalytic Addition of Olefinic C-H Bonds to Olefins
    F. Kakiuchi, Y. Tanaka, T. Sato, N. Chatani, and S. Murai
    Chem. Lett., (4), 679-680 (1995).
  • Catalytic Addition of Aromatic C-H Bonds to Acetylenes
    F. Kakiuchi, Y. Yamamoto, N. Chatani, and S. Murai
    Chem. Lett., (4), 681-682 (1995).
  • Co2(CO)8-Catalyzed Reaction of Aromatic Aldehydes with Hydrosilanes under Carbon Monoxide as 1 atm: Incorporation of CO into the Carbonyl Carbon Atom of Aldehydes
    N. Chatani, H. Tokuhisa, I. Kokubu, S. Fujii, and S. Murai
    J. Organomet. Chem., 499(1/2), 193-197 (1995).
  • Iridium-Catalyzed Reaction of Acetylene Hydrazones with a Hydrosilane and Carbon Monoxide. Synthesis of Nitrogen Heterocycles
    N. Chatani, S. Yamaguchi, Y. Fukumoto, and S. Murai
    Organometallics, 14(9), 4418-4420 (1995).
  • Directing Effect of Functional Groups in Ruthenium-Catalyzed Addition of Substituted Acetophenones to an Olefin
    M. Sonoda, F. Kakiuchi, N. Chatani, and S. Murai
    J. Organomet. Chem., 504(1/2), 151-152 (1995).

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