Ni-catalyzed Dimerization and Hydroperfluoroarylation of 1,3-Dienes
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Longzhi Zhu, Renhua Qiu, Tao Yang, Masahiro Ehara, Arumugam Sudalai, and Nobuaki Kambe
J. Org. Chem., in press.

Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents Catalyzed by Cp-Iron Complexes in the Presence of 1,3-Butadiene
Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu, and Nobuaki Kambe
Chem. Lett., 47 (6), 763–766 (2018).


Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: Mechanistic studies of four-component coupling and competing cross-coupling reactions
Takanori Iwasaki, Asuka Fukuoka, Wataru Yokoyama, Xin Min, Ichiro Hisaki, Tao Yang, Masahiro Ehara, Hitoshi Kuniyasu, and Nobuaki Kambe
Chem. Sci., 9, 2195-2211 (2018).
Highlighted in Synfacts 2018, 14, 0303



Cu-Catalyzed Reductive Coupling of Perfluoroarenes with 1,3-Dienes
Takanori Iwasaki , Kanako Okamoto, Hitoshi Kuniyasu, and Nobuaki Kambe
Chem. Lett., 46 (10), 1504-1507 (2017).

Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents
Takanori Iwasaki , Koji Yamashita, Hitoshi Kuniyasu, and Nobuaki Kambe
Org. Lett., 19 (14), 3691-3694 (2017).
Highlighted in Synfacts 2017, 13, 1070

Nickel-catalysed direct alkylation of thiophenes via double C(sp3)–H/C(sp2)–H bond cleavage: the importance of KH2PO4
Xie Wang, Peipei Xie, Renhua Qiu, Longzhi Zhu, Ting Liu, You Li, Takanori Iwasaki, Chak-Tong Au, Xinhua Xu, Yuanzhi Xia, Shuang-Feng Yin and Nobuaki Kambe
Chem. Commun., 53 (73), 8316-8319 (2017)

Intramolecular, Site-Selective, Iodine-Mediated, Amination of Unactivated (sp3)C–H Bonds for the Synthesis of Indoline Derivatives
Jinguo Long, Xin Cao, Longzhi Zhu, Renhua Qiu, Chak-Tong Au, Shuang-Feng Yin, Takanori Iwasaki, and Nobuaki Kambe
Org. Lett., 19 (11), 2793-2796 (2017).

Synthesis of Cyclic Nigerosylnigerose (CNN) Bis-Imidazolium Salts
Susumu Tsuda, Yuya Komatsu, Yohei Minami, Ryoji Ueda, Shin-ichi Fujiwara, Takanori Iwasaki, Hitoshi Kuniyasu, and Nobuaki Kambe
Heterocycles, 95 (2), 1197-1203 (2017).



Ni-Catalyzed C–C Couplings Using Alkyl Electrophiles
Takanori Iwasaki and Nobuaki Kambe
Top. Curr. Chem., 374, 66 (2016)

Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex
Takanori Iwasaki, Asuka Fukuoka, Xin Min, Wataru Yokoyama, Hitoshi Kuniyasu and Nobuaki Kambe
Org. Lett., 18 (19), 4868-4871 (2016)


Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents
Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Asian J., 11 (20), 2834-2837 (2016)


Regioselective Phosphorylation of myo-Inositol with BINOL Derived Phosphoramidites, and Its Application for Protozoan Lysophosphatidylinositol
Toshihiko Aiba, Masaki Sato, Daichi Umegaki, Takanori Iwasaki, Nobuaki Kambe, Koichi Fukase and Yukari Fujimoto
Org. Biomol. Chem., 14 (28), 6672-6675 (2016)


Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu and Nobuaki Kambe
Angew. Chem. Int. Ed., 55 (18), 5550-5554 (2016)
”Angew Chem誌のCover"に採用 されました。
"大阪大学のHP"で 取り上げられました。
Highlighted in Synfacts 2016, 12, 523



Copper-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Alkyl Fluorides and Grignard Reagents
Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu and Nobuaki Kambe
Angew. Chem. Int. Ed., 54 (32), 9347-9350 (2015)
"日経産業新聞(7月1日朝刊8 面)"で取り上げられました。
"大阪大学のHP"で 取り上げられました。



Nickel-catalyzed synthesis of diarylsulfides and sulfones via C–H bond functionalization of arylamides
Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki and Nobuaki Kambe
Org. Biomol. Chem., 13 (24), 6803-6813 (2015)



Copper-mediated thiolation of carbazole derivatives and related N-heterocycle compounds
Longzhi Zhu, Xin Cao, Renhua Qiu, Takanori Iwasaki, Vutukuri Prakash Reddy, Xinhua Xu, Shuang-Feng Yin and Nobuaki Kambe
RSC Adv., 5 (49), 39358-39365 (2015)



Regioselective Cis Insertion of DMAD into Au–P Bonds: Effect of Auxiliary Ligands on the Reaction Mechanism
Hitoshi Kuniyasu, Takuya Nakajima, Tamaki Takaki, Takanori Iwasaki and Nobuaki Kambe
Organometallics, 34 (7), 1373–1376 (2015)



AlCl3-catalyzed insertion of isocyanides into nitrogen-sulfur bonds of sulfenamides
Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Tetrahedron Lett., 56 (12), 1531-1534 (2015)


Palladium-Catalyzed Insertion Reactions of Isocyanides into Thiocarbamates and Selenocarbamates
Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 44 (4), 465-467 (2015)


Palladium Catalyzed Intramolecular Vinylselenation and Vinylthiolation of Allenes
Susumu Tsuda, Maiko Okuyama, Shin-ichi Fujiwara, Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Heterocycles, 90 (2), 1323-1331 (2015)


The Palladium-Catalyzed Intermolecular C-H Chalcogenation of Arenes
Renhua Qiu, Vutukuri Prakash Reddy, Takanori Iwasaki and Nobuaki Kambe
J. Org. Chem., 80 (1), 367-374 (2015)



Palladium-Catalyzed Decarbonylative Rearrangement of N-Allenyl Seleno- and Tellurocarbamates
Daisuke Shiro, Hiroyuki Nagai, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Heteroatom Chem., 25 (6), 518-524 (2014)


Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and Roles of Additives
Takanori Iwasaki, Reiko Imanishi, Ryohei Shimizu, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
J. Org. Chem., 79 (18), 8522-8532 (2014) (Featured Article)
Cover Picture


Halogen exchange by reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its mechanistic study
Hitoshi Kuniyasu, Atsushi Sanagawa, Takuya Nakajima, Takanori Iwasaki, Nobuaki Kambe, Karan Bobuatong and Masahiro Ehara
J. Organomet. Chem., 769, 34-37 (2014)


Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents
Takanori Iwasaki, Yoshinori Miyata, Ryo Akimoto, Yuuki Fujii, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 136 (26), 9260-9263 (2014)


The Co-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents. A New Route to Constructing Quaternary Carbon Centers
Takanori Iwasaki, Hiroaki Takagawa, Kanako Okamoto, Surya Prakash Singh, Hitoshi Kuniyasu and Nobuaki Kambe
Synthesis, 46 (12), 1583-1592 (2014)


Coupling Reactions Between sp3 Carbon Centers
Takanori Iwasaki and Nobuaki Kambe
Comprehensive Organic Synthesis, 2nd edition, Gary A. Molander and Paul Knochel (eds), Elsevier, 3, 337-391 (2014)



Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive
Takanori Iwasaki, Hiroaki Takagawa, Surya Prakash Singh, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 135 (26), 9604-9607 (2013)
Highlighted in Synfacts 2013, 9, 1002



Facile Halogen Exchange Method between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via σ-Bond Metathesis Supported by DFT Calculation
Atsushi Sanagawa, Hitoshi Kuniyasu, Takanori Iwasaki, Nobuaki Kambe, Karan Bobuatong and Masahiro Ehara
Chem. Lett., 42 (8), 831-832 (2013)



σ-Bond Metathesis between M-X and RC(O)X′(M = Pt, Pd; X, X = Cl, Br, I): Facile Determination of the Relative ΔG Values of the Oxidative Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional Theory Calculations, and Synthetic Applications
Hitoshi Kuniyasu, Atsushi Sanagawa, Daisuke Nakane, Takanori Iwasaki, Nobuaki Kambe, Karan Bobuatong, Yunpeng Lu and Masahiro Ehara
Organometallics, 32 (6), 2026-2032 (2013)



Rhodium-Catalyzed Intermolecular Oxidative Cross-Coupling of (Hetero)Arenes with Chalcogenophenes
Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki and Nobuaki Kambe
Org. Lett., 15 (6), 1290-1293 (2013)



Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C-H bond activation
Vutukuri Prakash Reddy, Takanori Iwasaki and Nobuaki Kambe
Org. Biomol. Chem., (11), 2249-2253 (2013)



Nickel-Butadiene Catalytic System for the Cross-Coupling of Bromoalkanoic Acids with Alkyl Grignard Reagents: A Practical and Versatile Method for Preparing Fatty Acids
Takanori Iwasaki, Kiyokazu Higashikawa, Vutukuri P. Reddy, Willbe W. S. Ho, Yukari Fujimoto, Koichi Fukase, Jun Terao, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Eur. J., 19 (9), 2956-2960 (2013)



Nickel-Catalyzed Coupling of Thiomethyl-Substituted 1,3-Benzothiazoles with Secondary Alkyl Grignard Reagents
Arash Ghaderi, Takanori Iwasaki, Asuka Fukuoka, Jun Terao and Nobuaki Kambe
Chem. Eur. J., 19 (9), 2951-2955 (2013)




Palladium-catalyzed vinylselenation of allenes
Shin-ichi Fujiwara, Maiko Okuyama, Susumu Tsuda, Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Tetrahedron, 68 (51), 10523-10529 (2012)



A Computational Study of Lithium Cuprate Mixed Aggregates
Chau Nguyen Duy Khiem, Le Ngoc Thach, Takanori Iwasaki, Nobuaki Kambe, Andrey A. Boguslavskiy and Lawrence M. Pratt
J. Phys. Chem. A., 116 (36), 9027-9032 (2012)



Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive
Ruwei Shen, Takanori Iwasaki, Jun Terao and Nobuaki Kambe
Chem. Commun., 48 (74), 9313-9315 (2012)



In Vitro Study of Photocurable Embolization Agent for Cerebral Aneurysms
Ayaka Ishikawa, Yasuhide Nakayama and Nobuaki Kambe
J Biotechnol Biomaterial, 2 (2), (2012)



Transition metal catalyzed alkylation at sp3-, sp2-, and sp-carbons
Nobuaki Kambe, Jun Terao and Takanori Iwasaki
J. Synth. Org. Chem. Jpn., 69 (11), 1271-1281 (2011)


The first example of palladium-catalyzed intermolecular allylaryloxylation of an internal alkyne by allyl aryl ethers
Hitoshi Kuniyasu, Kazunobu Takekawa, Atsushi Sanagawa, Takashi Wakasa, Takanori Iwasaki and Nobuaki Kambe
Tetrahedron Lett., 52 (42), 5501-5503 (2011)



Nickel-Catalyzed Alkyl Coupling Reactions: Evaluation of Computational Methods
Lawrence M. Pratt, Stewart Voit, Fabian N. Okeke and Nobuaki Kambe
J. Phys. Chem. A., 115 (11), 2281-2290 (2011)




Free radical addition of α-telluroesters to alkenes
Nobuaki Kambe, Li-Biao Han, Shin-Ichi Fujiwara and Noboru Sonoda
Heteroatom Chem., 22 (3-4), 518-522 (2011)


Pd-Catalyzed Cross-Coupling Reaction of Alkyl Halides
Nobuaki Kambe, Takanori Iwasaki and Jun Terao
Chem. Soc. Rev., 40 (10), 4937-4947 (2011)



Silver-Catalyzed Regioselective Carbomagnesiation of Alkynes with Alkyl Halides and Grignard Reagents
Nobuaki Kambe, Yuusuke Moriwaki, Yuuki Fujii, Takanori Iwasaki and Jun Terao
Org. Lett., 13 (17), 4656-4659 (2010)



Kinetic Studies of the Ni-Catalyzed Cross-Coupling of Alkyl Halides and a Tosylate with Butyl Grignard Reagent in the Presence of 1,3-Butadiene
Takanori Iwasaki, Asako Tsumura, Takehiro Omori, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Chem. Lett., 40 (9), 1024-1026 (2011)



Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular wire
Jun Terao, Kazuhiro Ikai, Nobuaki Kambe, Shu Seki, Akinori Saeki, Kento Ohkoshi, Tetsuaki Fujihara and Yasushi Tsuji
Chem. Commun., 47 (24), 6816-6818 (2011)



Cross-coupling of Grignard reagents with Alkyl Halides or Tosylates by the Use of Nickel or Palladium Containing Perovskite
Surya Prakash Singh, Takanori Iwasaki, Jun Terao and Nobuaki Kambe
Tetrahedron Lett., 52 (7), 774-776 (2011).




Palladium-catalyzed hydrophenoxycarbonylation of internal alkynes by phenol and CO: the use of Zn for the formation of active catalyst
Hitoshi Kuniyasu, Takahiro Yoshizawa and Nobuaki Kambe
Tetrahedron Lett., 51 (52), 6818-6821 (2010)



Synthesis of highly insulated molecular wires by polymerization of organic-soluble symmetrical linked inclusion complex monomers
Jun Terao, Susumu Tsuda, Keisuke Tsurui and Nobuaki Kambe
Macromol. Symp., 297 (1), 54-60 (2010)


Pd-Catalyzed Regioselective Iminothiolation of Alkynes: A Remarkable Effect of the CF3 Group of Iminosulfides
Yasunori Minami, Hitoshi Kuniyasu, Atsushi Sanagawa and Nobuaki Kambe
Org. Lett., 12 (17), 3744-3747 (2010)



Regioselectivity of Selenium-Mediated Carbonylation of Organolithium Compounds with Carbon Monoxide
Shin-ichi Fujiwara, Akira Nishiyama, Kazuhiro Okada, Hajime Maeda, Tsutomu Shin-ike, Noboru Sonoda and Nobuaki Kambe
Phosphorus Sulfur and Silicon and the Related Elements, 185 (5-6), 1117-1123 (2010)


Transition Metal-Catalyzed Cleavage of Carbon-Selenium Bond and Addition to Alkynes and Allenes
Shin-ichi Fujiwara, Masashi Toyofuku, Hitoshi Kuniyasu and Nobuaki Kambe
Pure Appl. Chem., 82 (3), 565-575 (2010)


Preparation and characteristic control of conducting polymer/metal oxide nano-hybrid films for solar energy conversion
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu Tsuda, Nobuaki Kambe and Susumu Kuwabata
Ceramic Engineering and Science Proceedings, 14, 35-49 (2010)


Nickel-Catalyzed Regioselective Carbomagnesation of Methylenecyclopropanes through a Site-Selective Carbon-Carbon Bond Cleavage
Jun Terao, Masahiro Tomita, Surya Prakash Singh and Nobuaki Kambe
Angew. Chem. Int. Ed., 49 (1), 144-147 (2010)




Insulated Molecular Wire with Highly Conductive π-Conjugated Polymer Core
Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru Taniguchi, Tomoji Kawai, Akinori Saeki and Shu Seki
J. Am. Chem. Soc., 131 (50), 18046-18047 (2009)



Ni-catalyzed regioselective three-component coupling of alkyl halides, arylalkynes, or enynes with R-M (M = MgX', ZnX')
Jun Terao, Fumiaki Bando and Nobuaki Kambe
Chem. Commun., (47), 7336-7338 (2009)




Synthesis of Organic-Soluble Conjugated Polyrotaxanes by Polymerization of Linked Rotaxanes
Jun Terao, Susumu Tsuda, Yuji Tanaka, Kentaro Okoshi, Tetsuaki Fujihara, Yasushi Tsuji and Nobuaki Kambe
J. Am. Chem. Soc., 131 (44), 16004-16005 (2009)



Non-catalytic conversion of C-F bonds of benzotrifuorides to C-C bonds using organoaluminium reagents
Jun Terao, Misaki Nakamura, and Nobuaki Kambe
Chem. Commun., (40), 6011-6013 (2009)



Nickel-catalyzed cross-coupling of unactivated alkyl halides and tosylate carrying a functional group with alkyl and phenyl Grignard reagents
Surya Prakash Singh, Jun Terao and Nobuaki Kambe
Tetrahedron Lett., 50 (40), 5644-5646 (2009)



Organometallics using organosulfur compounds: exchanges of information between catalytic and stoichiometric reactions
Hitoshi Kuniyasu and Nobuaki Kambe
有機合成化学協会誌, 67 (7), 701-713 (2009)



Organic conducting wire formation on a TiO2 nanocrystalline structure: towards long-lived charge separated systems
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu Tsuda, Nobuaki Kambe, Shu Seki and Susumu Kuwabata
Chem. Commun., (29), 4360-4362 (2009)



Synthesis of thiol esters by the use of carbonyl sulfide as a thiocarboxylation agent
Shin-ichi Fujiwara, Akira Asai, Yoshimasa Makita and Nobuaki Kambe
J. Sulfur Chem., 30 (3-4), 264-269 (2009)



Palladium-catalyzed intramolecular selenocarbamoylation of allenes with carbamoselenoates: a new entry to α,β-unsaturated lactams
Masashi Toyofuku, Erika Murase, Hiroyuki Nagai, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe
Eur. J. Org. Chem., 2009 (19), 3141-3144 (2009)



Transition-metal-catalyzed regioselective aroyl- and trifluoro-acetylthiolation of alkynes using thioesters
Yasunori Minami, Hitoshi Kuniyasu, Kiyoshi Miyafuji and Nobuaki Kambe
Chem. Commun., (21), 3080-3082 (2009)


Development of a Novel Nonviral Gene Silencing System That Is Effective Both in Vitro and in Vivo by Using a Star-Shaped Block Copolymer (Star Vector).
Taisuke Mori, Ayaka Ishikawa, Yasushi Nemoto, Nobuaki Kambe, Michiie Sakamoto and Yasuhide Nakayama
Bioconjugate Chem., 20 (6), 1262-1269 (2009)


A new entry to α-alkylidene-β-lactams by 4-exo-dig cyclization of carbamoyl radicals
Shin-ichi Fujiwara, Yoshihiko Shimizu, Yuji Imahori, Masashi Toyofuku, Tsutomu Shin-ike and Nobuaki Kambe
Tetrahedron Lett., 50 (26), 3628-3630 (2009)



Synthesis of a Linked [1]-[1]Rotaxane
Susumu Tsuda, Jun Terao, Keisuke Tsurui and Nobuaki Kambe
Chem. Lett., 38 (2), 190-191 (2009)


Silver-catalyzed carbomagnesiation of terminal aryl and silyl alynes and enynes in the presense of 1,2-dibromoethane
Yuuki Fujii, Jun Terao and Nobuaki Kambe
Chem. Commun., (9), 1115-1117 (2009)



Synthesis of linked symmetrical [3] and [5]rotaxanes using an oligomeric phenylene ethynylene (OPE) core skelton as a π-conjugated guest via double intramolecular self-inclusion
Susumu Tsuda, Jun Terao, Yuji Tanaka, Tomoka Maekawa and Nobuaki Kambe
Tetrahedron Lett., 50 (10), 1146-1150 (2009)



Synthesis of an Organic-soluble π-conjugated [1]Rotaxane
Susumu Tsuda, Jun Terao and Nobuaki Kambe
Chem. Lett., 10 (18), 76-77 (2009)


Structure, bonding, and aggregation of selenium-containing organolithium species
Lawrence M. Pratt, Shin-ichi Fujiwara and Nobuaki Kambe
Tetrahedron, 65 (5), 1017-1025 (2009)




Free radical tandem addition-cyclization of Te-phenyl N,N-dimethylcarbamotelluroate to 1,6-enynes
Shin-ichi Fujiwara, Yoshihiko Shimizu, Yoshimasa Makita, Tsutomu Shin-ike and Nobuaki Kambe
Heterocycles, 76 (2), 1577-1584 (2008)



Photodimerization and polymerization of PEG derivatives through radical coupling using photochemistry of dithiocarbamate
Yasuhide Nakayama, Ayaka Ishikawa, Ryo Sato, Kingo Uchida and Nobuaki Kambe
Polymer Journal, 40 (11), 1060-1066 (2008)



Titanocene-catalyzed alkylative dimerization of vinyl Grignard reagent using alkyl halides
Yuuki Fujii, Jun Terao, Yuichiro Kato and Nobuaki Kambe
Chem. Commun, (44), 5836-5838 (2008)



Insertion of Alkynes into an ArS-Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Hitoshi Kuniyasu, Kazunobu Takekawa, Fumikazu Yamashita, Kiyoshi Miyafuji, Shigehito Asano, Yasutomo Takai, Atsushi Ohtaka, Aoi Tanaka, Kunihiko Sugoh, Hideo Kurosawa and Nobuaki Kambe

Organometallics, 27 (18), 4788-4802 (2008)



Platinum-Catalyzed Selenoacylation of Allenes Leading to the Regioselective Formation of Functionalized Allyl Selenides
Masashi Toyofuku, Erika Murase, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe
Org. Let., 10 (18), 3957-3960 (2008)



Platinum-Catalyzed Intramolecular Vinylchalcogenation of Alkynes with β-Phenylchalcogeno Conjugated Amides
Masashi Toyofuku, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 130 (32), 10504-10505 (2008)



Titanocene-Catalyzed Regioselective Alkylation of Styrenes with Grignard Reagents Using -Bromoethyl Ethers, Thioethers, or Amines
Jun Terao, Yuichiro Kato and Nobuaki Kambe
Chem. Asian J., 3 (8), 1472-1478 (2008)



Carbon-carbon bond-forming reactions using alkyl fluorides
Jun Terao, Hirohisa Todo, Hiroyasu Watabe, Aki Ikumi, Yoshiaki Shinohara and Nobuaki Kambe
Pure Appl. Chem., 80 (5), 941-951 (2008)


One-Pot Syntheses of 2,3-Dihydrothiopyran-4-one Derivatives by Pd/Cu-Catalyzed Reactions of α,β-Unsaturated Thioesters with Propargyl Alcohols
Yasunori Minami, Hitoshi Kuniyasu and Nobuaki Kambe
Org. Lett., 10 (12), 2469-2472 (2008)



Cu-Catalyzed Regioselective Carbomagnesiation of dienes and enynes with sec- and tert-alkyl Grignard reagents
Hirosisa Todo, Jun Terao, Hideyuki Watanabe, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Comm., (11), 1332-1334 (2008)



Enhancement of Star Vector-Based Gene Delivery to Endothelial Cells by Addition of RGD-Peptide
Ayaka Ishikawa, Yue-Min Zhou, Nobuaki Kambe and Yasuhide Nakayama
Bioconjugate Chem., 19 (2), 558-561 (2008)


Plutinum-Catalyzed Regio- and Stereoselective Arylthiolation of Internal Alkynes
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Org. Lett., 10 (1), 101-104 (2008)




Definitive Evidence for the Insertion of Terminal Alkynes into ArylS-Pt Bonds: "o-Halogen Effect" in Stoichiometric and Catalytic Reaction
Hitoshi Kuniyasu, Fumikazu Yamashita, Jun Terao and Nobuaki Kambe
Angew. Chem. Int. Ed., 46 (31), 5929-5933 (2007)



Nickel-catalyzed dimerization coupling reactions of vinyl Grignard reagents with 3, 4-membered cyclic ethers and chlorosilanes
Yuuki Fujii, Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe and Nobuaki Kambe
Tetrahedron, 63 (28), 6635-6641 (2007)



Cu-Catalyzed Cross-Coupling Reaction of Grignard Reagents with primary-Alkyl Chlorides: Remerkable Effect of 1-Phenylpropyne
Jun Terao, Hirohisa Todo, Shameem Ara Begum, Hitoshi Kuniyasu and Nobuaki Kambe
Angew. Chem. Int. Ed., 46 (12), 2086-2089 (2007)



Pd-Catalyzed Coupling Reaction of Allyl and Propargyl Ethers with Chlorosilanes
Yoshitaka Naitoh, Fumiaki Bando, Jun Terao, Kazutaka Otsuki, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 36 (2), 236-237 (2007)


Conversion of (sp3)C-F Bonds of Alkyl Fluorides to (sp3)C-Heteroatom (Heteroatom = I, SR, SeR, TeR) Bonds by the Use of Magnesium Reagents Having Heteroatom Substituents
Shameem Ara Begum, Jun Terao and Nobuaki Kambe
Chem. Lett., 36 (1), 196-197 (2007)


Transition Metal Catalyzed Carbon-Silicon Bond Forming Reactions Using Chlorosilanes Promoted by Grignard Reagents
Jun Terao and Nobuaki Kambe
Chem. Record., 7 (1), 57-67 (2007)


"Conversion of a (sp3)C-F bond of alkyl fluorides to (sp3)C-X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents"
Jun Terao, Shameem Ara Begum, Yoshiaki Shinohara, Masahiro Tomita, Yoshitaka Naitoh and Nobuaki Kambe
Chem. Commun., (8), 855-857 (2007)



"Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing η3-allyl ligand as catalysts"
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Commun., (8), 825-827 (2007)



"Copper(I)-Catalyzed Highly Efficient Synthesis of Benzoselenazoles and Benzotellurazoles"
Shin-ichi Fujiwara, Yoshiaki Asanuma, Tsutomu Shin-ike and Nobuaki Kambe
J. Org. Chem., 72 (21), 808-8090 (2007)




"Silylation and alkylation of allenes using chlorosilanes and alkyl halides in the presence of palladium catalyst and Grignard reagents"
Yuuki Fujii, Jun Terao, Hitoshi Kuniyasu and Nobuaki Kambe
J. Organomett. Chem., 692 (1-3), 375-381 (2007)




"N-Carbonylation of Lithium Azaenolates of Amides, Formamides, Ureas, and Carbamates with Carbon Monoxide Mediated by Selenium"
Shin-ichi Fujiwara, Kazuhiro Okada, Yasukazu Shikano, Yoshihiko Shimizu, Tsutomu Shin-ike, Jun Terao, Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 72 (1), 273-276 (2006)



"Self-Organized Interconnect Method for Molecular Devices"
Masateru Taniguchi, Yoshihiro Nojima, Kazumichi Yokota, Jun Terao, Kimihiko, Sato, Nobuaki Kambe and Tomoji Kawai
J. Am. Chem. Soc., 128 (47), 15062-15063 (2006)



"Generation of Carbamoyl- and Thiocarbamoyllithium Synthons Having a Hydrogen(s) or an Aryl Group on the Nitrogen and Their Trapping with Carbonyl Electrophiles"
Nobuaki Kambe, Toru Inoue, Takanobu Takeda, Shin-ichi Fujiwara and Noboru Sonoda
J. Am. Chem. Soc., 128 (39), 12650-12651 (2006)



"Transition Metal-catalyzed Carbochalcogenation of Alkynes"
Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 35 (12), 1320-1325 (2006) Highlight Review


"Reactions of α,β-Unsaturated Thioesters with Platinum(0): Implication of a Dual Mechanism Leading to the Formation of Acyl Platinum"
Yasuhiro Minami, Tomohiro Kato, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Organometallics, 25 (12), 2949-2959 (2006)



"The first definitive example of oxidative addition of acyclic vinyl selenide to M(0) complex"
Hitoshi Kuniyasu, Tomohiro Kato, Masafumi Inoue, Jun Terao and Nobuaki Kambe
J. Organomet. Chem., 691 (9), 1873-1878 (2006)



"Transition Metal-Catalyzed C-C Bond Formation Reactions Using Alkyl Halides"
Jun Terao and Nobuaki Kambe
Bull. Chem. Soc. Jpn., 79 (5), 663-672 (2006) Award Account


""β-cis-SAr effect" on decarbonylation from α,β-unsaturated acyl and aroyl complexes"
Tomohiro Kato, Hitoshi Kuniyasu, Takamichi Kajiura, Yasunori Minami, Atsushi Ohtaka, Masanori Kinomoto, Jun Terao, Hideo Kurosawa and Nobuaki Kambe
Chem Commun., (8), 868-870 (2006)



"cis-to-trans Isomerization Promoted by Pyridine as a Crucial Step for the Selective Preparation of trans-Pt(SAr)(Cl)(PAr'3)2"
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Inorg. Chem., 45 (3), 1399-1404 (2006)



"Platinum-Catalyzed Reaction of Alkynes with ArI (Ar = aryl and thienyl) and Ar'SM (M = Na, K, and Sn(Bu-n)3): Three- vs Two-Component Cross-Coupling Reaction"
Hitoshi Kuniyasu, Fumikazu Yamashita, Takayoshi Hirai, Jia-Hai Ye, Shin-ichi Fujiwara and Nobuaki Kambe
Organometallics, 25 (3), 566-570 (2006)



"Pd-catalyzed thiocarbamoylation of terminal alkynes with sulfenamide and carbon monoxide"
Hitoshi Kuniyasu, Tomohiro Kato, Shigehito Asano, Jia-Hai Ye, Ohmori Takumi, Masaski Morita, Hiroshi Hiraike, Shin-ichi Fujiwara, Jun Terao, Hideo Kurosawa and Nobuaki Kambe
Tetrahedron Lett., 47 (7), 1141-1144 (2006)




"Zr-Catalyzed Coupling Reaction of Alkyl Halides, Tosylates, and Sulfates with b-Phenethyl Grignard Reagents via Styrene-Zirconate Intermediates"
Jun Terao, Shameem. Ara. Begum, Akihiro Oda and Nobuaki Kambe
Synlett, (11), 1783-1786 (2005)


"Palladium-Catalyzed Intramolecular Selenocarbamoylation of Alkynes with Carbamoselenoates: Formation of α-Alkylidene-β-lactam Frameworks"
Masashi Toyofuku, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 127 (27), 9706-9707 (2005)

"A New Entry of Carbothiolation: The Pt-Catalyzed Reaction of Furylthioesters with Terminal Alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Synlett, (7), 1161-1163 (2005)

"Carbonylation of Lithium Enolates of Esters and Amides with Carbon Monoxide and Selenium"
Nobuaki Kambe, Akira Nishiyama, Shin-ichi Fujiwara, Tsutomu Shin-ike and Noboru Sonoda
Phosphorus Sulfur Silicon Relat. Elem. 180 (3-4), 1001-1005 (2005)

"Thio-, Seleno-, and Telluro-Carboxylic Acid Esters"
Shin-ichi Fujiwara and Nobuaki Kambe S. Kato (Ed)
"Toppics in Current Chemistry: Chalcogen Carboxylic Acid Derivatives", Springer, 251, 87-140 (2005)

"ハロゲン化アルキル類のクロスカップリング反応を利用する(sp3)炭素-炭素結合生成の新手法"
寺尾 潤,神戸宣明
現代化学増刊 最新有機合成化学, 東京化学同人(奈良坂紘一・岩澤伸治編集),123-135

"Ni-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagents Using Alkyl Fluorides"
Jun Terao, Hiroyasu Watabe and Nobuaki Kambe
J. Am. Chem. Soc., 127 (11), 3656-3657 (2005)

"Pt-catalyzed regio- and stereoselective pyridylthiolation of terminal alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Tetrahedron Lett., 46 (1), 117-119 (2005)



"Nickel-Catalyzed Novel Coupling Reaction of Allyl Ethers with Chlorosilanes, Alkyl Tosylates, or Alkyl Halides Promoted by Vinyl Grignard Reagent Leading to Allylsilanes or Alkene"
Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe and Nobuaki Kambe
Adv. Synth. Catal., 346 (13-15), 1674-1678 (2004)

"Cross-Coupling Reaction of Alkyl Halides with Organometallic Reagents Using Transition-Metal Catalysts"
Jun Terao and Nobuaki Kambe
J. Synth. Org. Chem. Jpn., 62 (12), 1192-1204 (2004)


"Nickel-Catalyzed Cross-coupling Reaction of Alkyl Halides with Organozinc and Grignard Reagents Using 1,3,8,10-Tetraenes as Additives"
Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi and Nobuaki Kambe
Angew. Chem., Int. Ed., 43 (45), 6180-6182 (2004)

"Palladium-Catalyzed Dimerizative Disilylation of 1,3-Butadiene with Chlorosilane"
Jun Terao, Akihiro Oda and Nobuaki Kambe
Org. Lett., 6 (19), 3341-3344 (2004)

"Nickel-Catalyzed Regioselective Three Component Coupling Reaction of Alkyl Halides, Butadienes, and Ar-M (M = MgX, ZnX)"
Jun Terao, Shinsuke Nii, Firoz A. Chowdhury, Akifumi Nakamura and Nobuaki Kambe
Adv. Synth. Catal., 346 (8), 905-908 (2004)

"Pt-Catalyzed Regio- and Stereoselective Thienylthiolation of Alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 33 (9), 1148-1149 (2004)

"Selenoimidoylation of Alcohols with Selenium and Isocyanides and Its Application to the Synthesis of Selenium-Containing Heterocycles"
Yoshiaki Asanuma, Shin-ichi Fujiwara, Tsutomu Shin-ike and Nobuaki Kambe
J. Org. Chem., 69 (14), 4845-4848 (2004)

"Carbonylation of Lithium Enolates with Carbon Monoxide Mediated by Selenium"
Shin-ichi Fujiwara, Akira Nishiyama, Tsutomu Shin-ike, Nobuaki Kambe and Noboru Sonoda
Org. Lett., 6 (3), 453-455 (2004)

"Titanocene-Catalyzed Formation of Allylsilanes from Allyl Ethers and Chlorosilanes"
Shinsuke Nii, Jun Terao and Nobuaki Kambe
Tetrahedron Lett., 45 (8), 1699-1702 (2004)

"1,3-Butadiene as an Efficient Additive for Nickel, Palladium, or Copper-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents"
Jun Terao and Nobuaki Kambe
"Catalysts for Fine Chemical Synthesis, Vol. 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions", S. M. Roberts, J. Whittall, P. Mather, and P. McCormack (Eds.), John Wiley & Sons, Oxford, 128-133 (2004)

"Titanocene-Catalyzed Regioselective Carbomagnesation of Alkenes and Dienes"
Shinsuke Nii, Jun Terao and Nobuaki Kambe
J. Org. Chem., 69 (2), 573-576 (2004)

"Reaction Pathways of Zirconocene-Catalyzed Silylation of Alkenes with Chlorosilanes"
Jun Terao, Yingshi Jin, Kazushi Torii and Nobuaki Kambe
Tetrahedron, 60 (6), 1301-1308 (2004)

"アート型遷移金属錯体の創製と触媒反応への展開
炭素-炭素および炭素-ケイ素結合生成の新手法の開発を目指して "
寺尾 潤
化学と工業, 67 (2), 115-118 (2004)

"Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling"
Jun Terao, Andrew Tang, Jasper J. Michels, Alexander Krivokapic and Harry L. Anderson
Chem. Commun., (1), 56-57 (2004)



"Nickel-Catalyzed Dimerizative Carbosilylation of 1,3-Butadienes with Chlorosilanes and Grignard Reagents"
Jun Terao, Akihiro Oda, Aki Ikumi, Akifumi Nakamura, Hitoshi Kuniyasu and Nobuaki Kambe
Angew. Chem., Int. Ed. Engl., 42 (29), 3412-3414 (2003)

"Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Grignard Reagents"
Jun Terao, Aki Ikumi, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 125 (19), 5646-5647 (2003)

"Titanocene-Catalyzed Alkylation of Aryl-substituted Alkenes with Alkyl Halides"
Jun Terao, Hiroyasu Watabe, Masako Miyamoto and Nobuaki Kambe
Bull. Chem. Soc. Jpn., 76 (11), 2209-2214 (2003)

"The Pt-Catalyzed Carboselenation of Alkynes by Selenoesters"
Takayoshi Hirai, Hitoshi Kuniyasu, Tomohiro Kato, Yumi Kurata and Nobuaki Kambe
Org. Lett., 5 (21), 3871-3873 (2003)

"Pd-catalyzed Cross-coupling Reaction of Alkyl Tosylates and Bromides with Grignard Reagents in the Presence of 1,3-Butadiene"
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 32 (10), 890-891 (2003)



"Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents with Alkyl Halides and Tosylates: Remarkable Effect of 1,3-Butadienes"
Jun Terao, Hideyuki Watanabe, Aki Ikumi, Hitoshi Kuniyasu, Nobuaki Kambe
J. Am. Chem. Soc., 124 (16), 4222-4223 (2002)

"Zirconocene- or Titanocene Catalyzed Reactions Using Grignard Reagents"
Jun Terao and Nobuaki Kambe
in "Latest Frontiers of Organic Synthesis", Y. Kobayashi (Ed.), Research Signpost, India, 25-47 (2002)

"Stereoselective Synthesis of New Selenium-Containing Heterocycles byCyclocarbonylation of Aminoalkynes with Carbon Monoxide and Selenium"
Shin-ichi Fujiwara, Yasukazu Shikano, Tsutomu Shin-ike, Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 67 (17), 6275-6278 (2002)



"Titanocene-Catalyzed Reaction of Alkenes and Dienes with Alkyl Halides and Chlorosilanes"
Jun Terao and Nobuaki Kambe
"Journal of Synthetic Organic Chemistry Japan (Special Issue in English)", 59(11), 1044-1051 (2001)

"A Prototype of Transition-Metal-Catalyzed Carbothiolation of Alkynes"
Kunihiko Sugoh, Hitoshi Kuniyasu, Taeko Sugae, Atsushi Ohtaka, Yasutomo Takai, Aoi Tanaka, Chikako Machino, Nobuaki Kambe and Hideo Kurosawa
J. Am. Chem. Soc., 123 (21), 5108-5109 (2001)

"Photoinduced Group Transfer Radical Addition of Carbamotelluroloates to Acetylenes"
Shin-ichi Fujiwara, Yoshihiko Shimizu, Tsutomu Shin-ike and Nobuaki Kambe
Org. Lett., 3 (13), 2085-2088 (2001)

"Formation of 1,4-Disilyl-2-butenes from Vinyl Grignard Reagent and Chlorosilanes Catalyzed by a Titanocene Comples"
Hiroyasu Watabe, Jun Terao and Nobuaki Kambe
Org. Lett., 3(11), 1733-1735 (2001).

"Imidoyl Radicals as Synthons of Unstable Acyl Radicals"
Shin-ichi Fujiwara, Takahiro Matsuya, Hajime Maeda, Tsutomu Shin-ike, Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 66 (6), 2183-2185 (2001)



" Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents "
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, Nobuaki Kambe
"Imidoylation of Acidic Hydrocarbons with Selenium and Isocyanides: A New Synthetic Method for Preparation of Selenoimides"
Shin-ichi Fujiwara, Hajime Maeda, Takahiro Matsuya, Tsutomu Shin-ike, Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 65 (16), 5022-5025 (2000)

"The key to the Oxidative Addition of Vinyl Sulfide to M(0)"
Hitoshi Kuniyasu, Atushi Ohtaka, Takeo Nakazono, Masanori Kinomoto and Hideo Kurosawa
J. Am. Chem. Soc., 122 (10), 2375-2376 (2000)