Nickel-Catalyzed
Dimerization and
Alkylarylation of 1,3-Dienes with Alkyl Fluorides and
Aryl Grignard Reagents
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu and Nobuaki
Kambe
Angew.
Chem. Int. Ed., 55 (18), 5550-5554 (2016)
”Angew
Chem誌のCover"に採用
されました。
"大阪大学のHP"で
取り上げられました。
Highlighted in Synfacts 2016, 12, 523
Copper-Catalyzed
Regioselective Hydroalkylation of
1,3-Dienes
with Alkyl Fluorides and Grignard Reagents
Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu and
Nobuaki Kambe
Angew.
Chem. Int. Ed., 54 (32), 9347-9350 (2015)
"日経産業新聞(7月1日朝刊8
面)"で取り上げられました。
"大阪大学のHP"で
取り上げられました。
Nickel-catalyzed synthesis of diarylsulfides and sulfones via
C–H
bond functionalization of arylamides
Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki and Nobuaki Kambe
Org.
Biomol. Chem., 13 (24), 6803-6813 (2015)
Copper-mediated thiolation of carbazole derivatives and
related
N-heterocycle compounds
Longzhi Zhu, Xin Cao, Renhua Qiu, Takanori Iwasaki, Vutukuri Prakash
Reddy, Xinhua Xu, Shuang-Feng Yin and Nobuaki Kambe
RSC
Adv., 5 (49), 39358-39365 (2015)
Regioselective Cis Insertion of DMAD into Au–P Bonds: Effect
of
Auxiliary Ligands on the Reaction Mechanism
Hitoshi Kuniyasu, Takuya Nakajima, Tamaki Takaki, Takanori Iwasaki and
Nobuaki Kambe
Organometallics, 34 (7),
1373–1376 (2015)
AlCl3-catalyzed
insertion of isocyanides into
nitrogen-sulfur bonds of sulfenamides
Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki,
Hitoshi Kuniyasu and Nobuaki Kambe
Tetrahedron
Lett., 56 (12), 1531-1534 (2015)
Palladium-Catalyzed Insertion Reactions of Isocyanides into
Thiocarbamates and Selenocarbamates
Daisuke Shiro, Shin-ichi Fujiwara, Susumu Tsuda, Takanori Iwasaki,
Hitoshi Kuniyasu and Nobuaki Kambe
Chem.
Lett., 44 (4), 465-467 (2015)
Palladium Catalyzed Intramolecular Vinylselenation and Vinylthiolation
of Allenes
Susumu Tsuda, Maiko Okuyama, Shin-ichi Fujiwara, Takanori Iwasaki,
Hitoshi Kuniyasu and Nobuaki Kambe
Heterocycles,
90 (2), 1323-1331 (2015)
The Palladium-Catalyzed Intermolecular C-H Chalcogenation of Arenes
Renhua Qiu, Vutukuri Prakash Reddy, Takanori Iwasaki and Nobuaki Kambe
J.
Org. Chem., 80 (1), 367-374 (2015)
Palladium-Catalyzed
Decarbonylative Rearrangement
of
N-Allenyl
Seleno- and Tellurocarbamates
Daisuke Shiro, Hiroyuki Nagai, Shin-ichi Fujiwara, Susumu Tsuda,
Takanori Iwasaki, Hitoshi Kuniyasu and Nobuaki Kambe
Heteroatom
Chem., 25 (6), 518-524 (2014)
Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon
Additives: Efficiency of Catalyst and Roles of Additives
Takanori Iwasaki, Reiko Imanishi, Ryohei Shimizu, Hitoshi Kuniyasu, Jun
Terao and Nobuaki Kambe
J.
Org. Chem., 79 (18), 8522-8532 (2014) (Featured Article)
Cover Picture
Halogen exchange by reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br,
I) and its mechanistic study
Hitoshi Kuniyasu, Atsushi Sanagawa, Takuya Nakajima, Takanori Iwasaki,
Nobuaki Kambe, Karan Bobuatong and Masahiro Ehara
J. Organomet. Chem., 769,
34-37 (2014)
Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl
Ethers with Grignard Reagents
Takanori Iwasaki, Yoshinori Miyata, Ryo Akimoto, Yuuki Fujii, Hitoshi
Kuniyasu and Nobuaki Kambe
J.
Am. Chem. Soc., 136 (26), 9260-9263 (2014)
The Co-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl
Grignard Reagents. A New Route to Constructing Quaternary Carbon Centers
Takanori Iwasaki, Hiroaki Takagawa, Kanako Okamoto, Surya Prakash
Singh, Hitoshi Kuniyasu and Nobuaki Kambe
Synthesis,
46 (12), 1583-1592 (2014)
Coupling Reactions Between sp3
Carbon Centers
Takanori Iwasaki and Nobuaki Kambe
Comprehensive Organic Synthesis,
2nd edition,
Gary A. Molander and Paul Knochel (eds), Elsevier, 3, 337-391 (2014)
Co-Catalyzed
Cross-Coupling of Alkyl Halides with
Tertiary
Alkyl Grignard Reagents Using a 1,3-Butadiene Additive
Takanori Iwasaki, Hiroaki Takagawa, Surya Prakash Singh, Hitoshi
Kuniyasu and Nobuaki Kambe
J.
Am. Chem. Soc., 135 (26), 9604-9607 (2013)
Highlighted in Synfacts 2013, 9, 1002
Facile Halogen Exchange Method between Au(Cl)(L) and
MeC(O)X (L
= PPh3 and IPr; X = Br and I) via
σ-Bond Metathesis
Supported by DFT Calculation
Atsushi Sanagawa, Hitoshi Kuniyasu, Takanori Iwasaki, Nobuaki Kambe,
Karan Bobuatong and Masahiro Ehara
Chem. Lett., 42 (8),
831-832 (2013)
σ-Bond Metathesis between M-X and RC(O)X′(M = Pt, Pd; X, X = Cl, Br,
I): Facile Determination of the Relative ΔG Values of the Oxidative
Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional
Theory Calculations, and Synthetic Applications
Hitoshi Kuniyasu, Atsushi Sanagawa, Daisuke Nakane, Takanori Iwasaki,
Nobuaki Kambe,
Karan Bobuatong, Yunpeng Lu and Masahiro Ehara
Organometallics,
32 (6), 2026-2032 (2013)
Rhodium-Catalyzed Intermolecular Oxidative Cross-Coupling of
(Hetero)Arenes with Chalcogenophenes
Vutukuri Prakash Reddy, Renhua Qiu, Takanori Iwasaki and Nobuaki Kambe
Org.
Lett., 15 (6), 1290-1293 (2013)
Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by
rhodium-catalyzed intramolecular double C－H bond activation
Vutukuri Prakash Reddy, Takanori Iwasaki and Nobuaki Kambe
Org. Biomol. Chem., (11),
2249-2253 (2013)
Nickel-Butadiene Catalytic System for the Cross-Coupling of
Bromoalkanoic
Acids with Alkyl Grignard Reagents: A Practical and Versatile Method
for
Preparing Fatty Acids
Takanori Iwasaki, Kiyokazu Higashikawa, Vutukuri P. Reddy, Willbe W. S.
Ho,
Yukari Fujimoto, Koichi Fukase, Jun Terao, Hitoshi Kuniyasu and
Nobuaki Kambe
Chem. Eur. J., 19 (9),
2956-2960 (2013)
Nickel-Catalyzed
Coupling of
Thiomethyl-Substituted
1,3-Benzothiazoles
with Secondary Alkyl Grignard Reagents
Arash Ghaderi, Takanori Iwasaki, Asuka Fukuoka, Jun Terao and Nobuaki
Kambe
Chem. Eur. J., 19 (9),
2951-2955 (2013)
Palladium-catalyzed
vinylselenation of allenes
Shin-ichi Fujiwara, Maiko Okuyama, Susumu Tsuda, Takanori Iwasaki,
Hitoshi
Kuniyasu and Nobuaki Kambe
Tetrahedron, 68 (51),
10523-10529 (2012)
A Computational Study of Lithium Cuprate Mixed Aggregates
Chau Nguyen Duy Khiem, Le Ngoc Thach, Takanori Iwasaki, Nobuaki Kambe,
Andrey A. Boguslavskiy and Lawrence M. Pratt
J. Phys. Chem. A., 116
(36), 9027-9032 (2012)
Copper-catalyzed coupling reaction of unactivated secondary alkyl
iodides with alkyl Grignard reagents in the presence of 1,3-butadiene
as an effective additive
Ruwei Shen, Takanori Iwasaki, Jun Terao and Nobuaki Kambe
Chem. Commun., 48 (74),
9313-9315 (2012)
In Vitro Study of Photocurable Embolization Agent for Cerebral
Aneurysms
Ayaka Ishikawa, Yasuhide Nakayama and Nobuaki Kambe
J Biotechnol Biomaterial,
2 (2), (2012)
Transition
metal catalyzed alkylation at sp3-,
sp2-,
and
sp-carbons
Nobuaki Kambe, Jun Terao and Takanori Iwasaki
J. Synth. Org. Chem. Jpn.,
69 (11), 1271-1281
(2011)
The first example of palladium-catalyzed intermolecular
allylaryloxylation
of an internal alkyne by allyl aryl ethers
Hitoshi Kuniyasu, Kazunobu Takekawa, Atsushi Sanagawa, Takashi Wakasa,
Takanori Iwasaki and Nobuaki Kambe
Tetrahedron Lett., 52
(42), 5501-5503 (2011)
Nickel-Catalyzed Alkyl Coupling Reactions: Evaluation of Computational
Methods
Lawrence M. Pratt, Stewart Voit, Fabian N. Okeke and Nobuaki Kambe
J. Phys. Chem. A., 115
(11), 2281-2290 (2011)
Free radical addition of α-telluroesters to alkenes
Nobuaki Kambe, Li-Biao Han, Shin-Ichi Fujiwara and Noboru Sonoda
Heteroatom Chem., 22
(3-4), 518-522 (2011)
Pd-Catalyzed Cross-Coupling Reaction of Alkyl Halides
Nobuaki Kambe, Takanori Iwasaki and Jun Terao
Chem.
Soc. Rev., 40 (10), 4937-4947 (2011)
Silver-Catalyzed Regioselective Carbomagnesiation of Alkynes with Alkyl
Halides and Grignard Reagents
Nobuaki Kambe, Yuusuke Moriwaki, Yuuki Fujii, Takanori Iwasaki and Jun
Terao
Org.
Lett., 13 (17), 4656-4659 (2010)
Kinetic Studies of the Ni-Catalyzed Cross-Coupling of Alkyl Halides and
a Tosylate with Butyl Grignard Reagent in the Presence of 1,3-Butadiene
Takanori Iwasaki, Asako Tsumura, Takehiro Omori, Hitoshi Kuniyasu, Jun
Terao and Nobuaki Kambe
Chem.
Lett., 40 (9), 1024-1026 (2011)
Synthesis of a head-to-tail-type cyclodextrin-based insulated molecular
wire
Jun Terao, Kazuhiro Ikai, Nobuaki Kambe, Shu Seki, Akinori Saeki, Kento
Ohkoshi, Tetsuaki Fujihara and Yasushi Tsuji
Chem. Commun., 47 (24),
6816-6818 (2011)
Cross-coupling of Grignard reagents with Alkyl Halides or Tosylates by
the Use of Nickel or Palladium Containing Perovskite
Surya Prakash Singh, Takanori Iwasaki, Jun Terao and Nobuaki Kambe
Tetrahedron Lett., 52
(7), 774-776 (2011).
Palladium-catalyzed
hydrophenoxycarbonylation of
internal
alkynes by phenol and CO: the use of Zn for the formation of active
catalyst
Hitoshi Kuniyasu, Takahiro Yoshizawa and Nobuaki Kambe
Tetrahedron
Lett., 51 (52), 6818-6821 (2010)
Synthesis of highly insulated molecular wires by polymerization of
organic-soluble symmetrical linked inclusion complex monomers
Jun Terao, Susumu Tsuda, Keisuke Tsurui and Nobuaki Kambe
Macromol.
Symp., 297 (1), 54-60 (2010)
Pd-Catalyzed Regioselective Iminothiolation of Alkynes: A Remarkable
Effect of the CF3 Group of Iminosulfides
Yasunori Minami, Hitoshi Kuniyasu, Atsushi Sanagawa and Nobuaki Kambe
Org.
Lett., 12 (17), 3744-3747 (2010)
Regioselectivity of Selenium-Mediated Carbonylation of Organolithium
Compounds with Carbon Monoxide
Shin-ichi Fujiwara, Akira Nishiyama, Kazuhiro Okada, Hajime Maeda,
Tsutomu Shin-ike, Noboru Sonoda and Nobuaki Kambe
Phosphorus
Sulfur and Silicon and the Related Elements, 185 (5-6),
1117-1123
(2010)
Transition Metal-Catalyzed Cleavage of Carbon-Selenium Bond and
Addition to Alkynes and Allenes
Shin-ichi Fujiwara, Masashi Toyofuku, Hitoshi Kuniyasu and Nobuaki
Kambe
Pure
Appl. Chem., 82 (3), 565-575 (2010)
Preparation and characteristic control of conducting polymer/metal
oxide nano-hybrid films for solar energy conversion
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu
Tsuda, Nobuaki Kambe and Susumu Kuwabata
Ceramic
Engineering and Science Proceedings, 14, 35-49 (2010)
Nickel-Catalyzed Regioselective Carbomagnesation of
Methylenecyclopropanes through a Site-Selective Carbon-Carbon Bond
Cleavage
Jun Terao, Masahiro Tomita, Surya Prakash Singh and Nobuaki Kambe
Angew.
Chem. Int. Ed., 49 (1), 144-147 (2010)
Insulated
Molecular Wire with Highly Conductive
π-Conjugated
Polymer Core
Jun Terao, Yuji Tanaka, Susumu Tsuda, Nobuaki Kambe, Masateru
Taniguchi, Tomoji Kawai, Akinori Saeki and Shu Seki
J.
Am.
Chem. Soc., 131 (50), 18046-18047 (2009)
Ni-catalyzed
regioselective three-component
coupling
of
alkyl
halides, arylalkynes, or enynes with R-M (M = MgX', ZnX')
Jun Terao, Fumiaki Bando and Nobuaki Kambe
Chem.
Commun.,
(47), 7336-7338 (2009)
Synthesis
of Organic-Soluble Conjugated
Polyrotaxanes
by
Polymerization of Linked Rotaxanes
Jun Terao, Susumu Tsuda, Yuji Tanaka, Kentaro Okoshi, Tetsuaki
Fujihara, Yasushi Tsuji and Nobuaki Kambe
J.
Am.
Chem. Soc., 131 (44), 16004-16005 (2009)
Non-catalytic
conversion of C-F bonds of
benzotrifuorides
to
C-C bonds using organoaluminium reagents
Jun Terao, Misaki Nakamura, and Nobuaki Kambe
Chem.
Commun.,
(40), 6011-6013 (2009)
Nickel-catalyzed
cross-coupling of unactivated
alkyl
halides
and tosylate carrying a functional group with alkyl and phenyl Grignard
reagents
Surya Prakash Singh, Jun Terao and Nobuaki Kambe
Tetrahedron
Lett., 50 (40), 5644-5646 (2009)
Organometallics
using organosulfur compounds:
exchanges
of
information between catalytic and stoichiometric reactions
Hitoshi Kuniyasu and Nobuaki Kambe
有機合成化学協会誌, 67 (7),
701-713 (2009)
Organic
conducting wire formation on a TiO2
nanocrystalline
structure: towards long-lived charge separated systems
Yasuhiro Tachibana, Satoshi Makuta, Yasuhide Otsuka, Jun Terao, Susumu
Tsuda, Nobuaki Kambe, Shu Seki and Susumu Kuwabata
Chem.
Commun.,
(29), 4360-4362 (2009)
Synthesis
of thiol esters by the use of carbonyl
sulfide
as
a
thiocarboxylation agent
Shin-ichi Fujiwara, Akira Asai, Yoshimasa Makita and Nobuaki Kambe
J.
Sulfur Chem., 30 (3-4), 264-269 (2009)
Palladium-catalyzed
intramolecular
selenocarbamoylation
of
allenes with carbamoselenoates: a new entry to α,β-unsaturated lactams
Masashi Toyofuku, Erika Murase, Hiroyuki Nagai, Shin-ichi Fujiwara,
Tsutomu Shin-ike, Hitoshi Kuniyasu and Nobuaki Kambe
Eur.
J. Org. Chem., 2009 (19), 3141-3144 (2009)
Transition-metal-catalyzed
regioselective aroyl-
and
trifluoro-acetylthiolation of alkynes using thioesters
Yasunori Minami, Hitoshi Kuniyasu, Kiyoshi Miyafuji and Nobuaki Kambe
Chem.
Commun., (21), 3080-3082 (2009)
Development
of a Novel Nonviral Gene Silencing
System
That
Is
Effective Both in Vitro and in Vivo by Using a Star-Shaped Block
Copolymer (Star Vector).
Taisuke Mori, Ayaka Ishikawa, Yasushi Nemoto, Nobuaki Kambe, Michiie
Sakamoto and Yasuhide Nakayama
Bioconjugate
Chem., 20 (6), 1262-1269 (2009)
A new
entry to α-alkylidene-β-lactams by 4-exo-dig
cyclization
of carbamoyl radicals
Shin-ichi Fujiwara, Yoshihiko Shimizu, Yuji Imahori, Masashi Toyofuku,
Tsutomu Shin-ike and Nobuaki Kambe
Tetrahedron
Lett., 50 (26), 3628-3630 (2009)
Synthesis
of a Linked [1]-[1]Rotaxane
Susumu Tsuda, Jun Terao, Keisuke Tsurui and Nobuaki Kambe
Chem.
Lett., 38 (2), 190-191 (2009)
Silver-catalyzed
carbomagnesiation of terminal
aryl
and
silyl
alynes and enynes in the presense of 1,2-dibromoethane
Yuuki Fujii, Jun Terao and Nobuaki Kambe
Chem.
Commun., (9), 1115-1117 (2009)
Synthesis
of linked symmetrical [3] and
[5]rotaxanes
using
an
oligomeric phenylene ethynylene (OPE) core skelton as a π-conjugated
guest via double intramolecular self-inclusion
Susumu Tsuda, Jun Terao, Yuji Tanaka, Tomoka Maekawa and Nobuaki Kambe
Tetrahedron
Lett., 50 (10), 1146-1150 (2009)
Synthesis
of an Organic-soluble π-conjugated
[1]Rotaxane
Susumu Tsuda, Jun Terao and Nobuaki Kambe
Chem.
Lett., 10 (18), 76-77 (2009)
Structure,
bonding, and aggregation of
selenium-containing
organolithium species
Lawrence M. Pratt, Shin-ichi Fujiwara and Nobuaki Kambe
Tetrahedron,
65 (5), 1017-1025 (2009)
Free
radical tandem addition-cyclization of
Te-phenyl
N,N-dimethylcarbamotelluroate to 1,6-enynes
Shin-ichi Fujiwara, Yoshihiko Shimizu, Yoshimasa Makita, Tsutomu
Shin-ike and Nobuaki Kambe
Heterocycles,
76 (2), 1577-1584 (2008)
Photodimerization
and polymerization of PEG
derivatives
through radical coupling using photochemistry of dithiocarbamate
Yasuhide Nakayama, Ayaka Ishikawa, Ryo Sato, Kingo Uchida and Nobuaki
Kambe
Polymer
Journal, 40 (11), 1060-1066 (2008)
Titanocene-catalyzed
alkylative dimerization of
vinyl
Grignard
reagent using alkyl halides
Yuuki Fujii, Jun Terao, Yuichiro Kato and Nobuaki Kambe
Chem.
Commun, (44), 5836-5838 (2008)
Insertion of Alkynes into an ArS－Pt
Bond:
Regio- and Stereoselective Thermal Reactions, Facilitation by
“o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences
Depending on the Ancillary Ligand, and Application to a Catalytic
Reaction
Hitoshi Kuniyasu, Kazunobu Takekawa, Fumikazu Yamashita, Kiyoshi
Miyafuji, Shigehito Asano, Yasutomo Takai, Atsushi Ohtaka, Aoi Tanaka,
Kunihiko Sugoh, Hideo Kurosawa and Nobuaki Kambe
Organometallics,
27 (18), 4788-4802 (2008)
Platinum-Catalyzed
Selenoacylation of Allenes
Leading
to
the
Regioselective Formation of Functionalized Allyl Selenides
Masashi Toyofuku, Erika Murase, Shin-ichi Fujiwara, Tsutomu Shin-ike,
Hitoshi Kuniyasu and Nobuaki Kambe
Org.
Let., 10 (18), 3957-3960 (2008)
Platinum-Catalyzed
Intramolecular
Vinylchalcogenation
of
Alkynes with β-Phenylchalcogeno Conjugated Amides
Masashi Toyofuku, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi
Kuniyasu and Nobuaki Kambe
J.
Am.
Chem. Soc., 130 (32), 10504-10505 (2008)
Titanocene-Catalyzed Regioselective Alkylation of Styrenes with
Grignard Reagents Using -Bromoethyl Ethers, Thioethers, or Amines
Jun Terao, Yuichiro Kato and Nobuaki Kambe
Chem.
Asian J., 3 (8), 1472-1478 (2008)
Carbon-carbon bond-forming reactions using alkyl fluorides
Jun Terao, Hirohisa Todo, Hiroyasu Watabe, Aki Ikumi, Yoshiaki
Shinohara and Nobuaki Kambe
Pure
Appl. Chem., 80 (5), 941-951 (2008)
One-Pot Syntheses of 2,3-Dihydrothiopyran-4-one Derivatives by
Pd/Cu-Catalyzed Reactions of α,β-Unsaturated Thioesters with Propargyl
Alcohols
Yasunori Minami, Hitoshi Kuniyasu and Nobuaki Kambe
Org.
Lett., 10 (12), 2469-2472 (2008)
Cu-Catalyzed Regioselective Carbomagnesiation of dienes and enynes with
sec- and tert-alkyl Grignard
reagents
Hirosisa Todo, Jun Terao, Hideyuki Watanabe, Hitoshi Kuniyasu and
Nobuaki Kambe
Chem.
Comm., (11), 1332-1334 (2008)
Enhancement of Star Vector-Based Gene Delivery to Endothelial Cells by
Addition of RGD-Peptide
Ayaka Ishikawa, Yue-Min Zhou, Nobuaki Kambe and Yasuhide Nakayama
Bioconjugate
Chem., 19 (2), 558-561 (2008)
Plutinum-Catalyzed Regio- and Stereoselective Arylthiolation of
Internal Alkynes
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Org.
Lett., 10 (1), 101-104 (2008)
Definitive
Evidence for the Insertion of Terminal
Alkynes
into
ArylS-Pt Bonds: "o-Halogen Effect" in Stoichiometric
and
Catalytic Reaction
Hitoshi Kuniyasu, Fumikazu Yamashita, Jun Terao and Nobuaki Kambe
Angew.
Chem. Int. Ed., 46 (31), 5929-5933 (2007)
Nickel-catalyzed dimerization coupling reactions of vinyl Grignard
reagents with 3, 4-membered cyclic ethers and chlorosilanes
Yuuki Fujii, Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe and Nobuaki
Kambe
Tetrahedron,
63 (28), 6635-6641 (2007)
Cu-Catalyzed Cross-Coupling Reaction of Grignard Reagents with primary-Alkyl
Chlorides: Remerkable Effect of 1-Phenylpropyne
Jun Terao, Hirohisa Todo, Shameem Ara Begum, Hitoshi Kuniyasu and
Nobuaki Kambe
Angew. Chem. Int. Ed., 46
(12), 2086-2089
(2007)
Pd-Catalyzed Coupling Reaction of Allyl and Propargyl Ethers with
Chlorosilanes
Yoshitaka Naitoh, Fumiaki Bando, Jun Terao, Kazutaka Otsuki, Hitoshi
Kuniyasu and Nobuaki Kambe
Chem. Lett., 36 (2),
236-237 (2007)
Conversion of (sp3)C-F Bonds of Alkyl Fluorides to (sp3)C-Heteroatom
(Heteroatom = I, SR, SeR, TeR) Bonds by the Use of Magnesium Reagents
Having
Heteroatom Substituents
Shameem Ara Begum, Jun Terao and Nobuaki Kambe
Chem. Lett., 36 (1),
196-197 (2007)
Transition Metal Catalyzed Carbon-Silicon Bond Forming Reactions Using
Chlorosilanes Promoted by Grignard Reagents
Jun Terao and Nobuaki Kambe
Chem. Record., 7 (1),
57-67 (2007)
"Conversion of a (sp3)C-F bond of alkyl fluorides to (sp3)C-X (X = Cl,
C, H, O, S, Se, Te, N) bonds using organoaluminium reagents"
Jun Terao, Shameem Ara Begum, Yoshiaki Shinohara, Masahiro Tomita,
Yoshitaka Naitoh and Nobuaki Kambe
Chem.
Commun., (8), 855-857 (2007)
"Cross-coupling of alkyl halides with Grignard reagents using nickel
and palladium complexes bearing η3-allyl ligand as catalysts"
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu and Nobuaki Kambe
Chem.
Commun., (8), 825-827 (2007)
"Copper(I)-Catalyzed Highly Efficient Synthesis of Benzoselenazoles and
Benzotellurazoles"
Shin-ichi Fujiwara, Yoshiaki Asanuma, Tsutomu Shin-ike and Nobuaki Kambe
J.
Org. Chem., 72 (21), 808-8090 (2007)
"Silylation and alkylation of allenes using chlorosilanes and alkyl
halides in the presence of palladium catalyst and Grignard reagents"
Yuuki Fujii, Jun Terao, Hitoshi Kuniyasu and Nobuaki Kambe
J. Organomett. Chem., 692
(1-3), 375-381 (2007)
"N-Carbonylation
of Lithium Azaenolates of
Amides,
Formamides, Ureas, and Carbamates with Carbon Monoxide Mediated by
Selenium"
Shin-ichi Fujiwara, Kazuhiro Okada, Yasukazu Shikano, Yoshihiko
Shimizu,
Tsutomu Shin-ike, Jun Terao, Nobuaki Kambe and Noboru Sonoda
J.
Org. Chem., 72 (1), 273-276 (2006)
"Self-Organized Interconnect Method for Molecular Devices"
Masateru Taniguchi, Yoshihiro Nojima, Kazumichi Yokota, Jun Terao,
Kimihiko, Sato, Nobuaki Kambe and Tomoji Kawai
J.
Am.
Chem. Soc., 128 (47), 15062-15063 (2006)
"Generation of Carbamoyl- and Thiocarbamoyllithium Synthons Having a
Hydrogen(s) or an Aryl Group on the Nitrogen and Their Trapping with
Carbonyl Electrophiles"
Nobuaki Kambe, Toru Inoue, Takanobu Takeda, Shin-ichi Fujiwara and
Noboru Sonoda
J. Am. Chem. Soc., 128
(39), 12650-12651 (2006)
"Transition Metal-catalyzed Carbochalcogenation of Alkynes"
Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 35 (12),
1320-1325 (2006) Highlight
Review
"Reactions of α,β-Unsaturated Thioesters with Platinum(0):
Implication of a Dual Mechanism Leading to the Formation of Acyl
Platinum"
Yasuhiro Minami, Tomohiro Kato, Hitoshi Kuniyasu, Jun Terao and Nobuaki
Kambe
Organometallics, 25 (12),
2949-2959 (2006)
"The first definitive example of oxidative addition of acyclic vinyl
selenide to M(0) complex"
Hitoshi Kuniyasu, Tomohiro Kato, Masafumi Inoue, Jun Terao and Nobuaki
Kambe
J. Organomet. Chem., 691
(9), 1873-1878 (2006)
"Transition Metal-Catalyzed C-C Bond Formation Reactions Using Alkyl
Halides"
Jun Terao and Nobuaki Kambe
Bull. Chem. Soc. Jpn., 79
(5), 663-672 (2006) Award
Account
""β-cis-SAr effect" on decarbonylation from
α，β-unsaturated acyl
and aroyl complexes"
Tomohiro Kato, Hitoshi Kuniyasu, Takamichi Kajiura, Yasunori Minami,
Atsushi Ohtaka, Masanori Kinomoto, Jun Terao, Hideo Kurosawa and
Nobuaki Kambe
Chem Commun., (8),
868-870 (2006)
"cis-to-trans Isomerization Promoted by Pyridine as a Crucial Step for
the Selective Preparation of trans-Pt(SAr)(Cl)(PAr'3)2"
Fumikazu Yamashita, Hitoshi Kuniyasu, Jun Terao and Nobuaki Kambe
Inorg. Chem., 45 (3),
1399-1404 (2006)
"Platinum-Catalyzed Reaction of Alkynes with ArI (Ar = aryl and
thienyl) and Ar'SM (M = Na, K, and Sn(Bu-n)3):
Three- vs
Two-Component Cross-Coupling Reaction"
Hitoshi Kuniyasu, Fumikazu Yamashita, Takayoshi Hirai, Jia-Hai Ye,
Shin-ichi Fujiwara and Nobuaki Kambe
Organometallics, 25 (3),
566-570 (2006)
"Pd-catalyzed thiocarbamoylation of terminal alkynes with sulfenamide
and carbon monoxide"
Hitoshi Kuniyasu, Tomohiro Kato, Shigehito Asano, Jia-Hai Ye, Ohmori
Takumi, Masaski Morita, Hiroshi Hiraike, Shin-ichi Fujiwara, Jun Terao,
Hideo Kurosawa and Nobuaki Kambe
Tetrahedron
Lett., 47 (7), 1141-1144 (2006)
"Zr-Catalyzed
Coupling Reaction of Alkyl Halides,
Tosylates,
and Sulfates
with b-Phenethyl Grignard Reagents via Styrene-Zirconate Intermediates"
Jun Terao, Shameem. Ara. Begum, Akihiro Oda and Nobuaki Kambe
Synlett,
(11), 1783-1786 (2005)
"Palladium-Catalyzed Intramolecular Selenocarbamoylation of Alkynes
with Carbamoselenoates: Formation of α-Alkylidene-β-lactam Frameworks"
Masashi Toyofuku, Shin-ichi Fujiwara, Tsutomu Shin-ike, Hitoshi
Kuniyasu and Nobuaki Kambe
J.
Am. Chem. Soc., 127 (27), 9706-9707 (2005)
"A New Entry of Carbothiolation: The Pt-Catalyzed Reaction of
Furylthioesters with Terminal Alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Synlett,
(7), 1161-1163 (2005)
"Carbonylation of Lithium Enolates of Esters and Amides with Carbon
Monoxide and Selenium"
Nobuaki Kambe, Akira Nishiyama, Shin-ichi Fujiwara, Tsutomu Shin-ike
and Noboru Sonoda
Phosphorus
Sulfur Silicon Relat. Elem. 180 (3-4), 1001-1005
(2005)
"Thio-, Seleno-, and Telluro-Carboxylic Acid Esters"
Shin-ichi Fujiwara and Nobuaki Kambe S. Kato (Ed)
"Toppics
in Current Chemistry: Chalcogen Carboxylic Acid Derivatives",
Springer, 251, 87-140 (2005)
"ハロゲン化アルキル類のクロスカップリング反応を利用する(sp3)炭素－炭素結合生成の新手法"
寺尾 潤，神戸宣明
現代化学増刊 最新有機合成化学, 東京化学同人（奈良坂紘一・岩澤伸治編集），123-135
"Ni-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagents Using
Alkyl Fluorides"
Jun Terao, Hiroyasu Watabe and Nobuaki Kambe
J. Am. Chem. Soc., 127
(11), 3656-3657 (2005)
"Pt-catalyzed regio- and stereoselective pyridylthiolation of terminal
alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Tetrahedron
Lett., 46 (1), 117-119 (2005)
"Nickel-Catalyzed
Novel Coupling Reaction of Allyl
Ethers
with
Chlorosilanes, Alkyl Tosylates, or Alkyl Halides Promoted by Vinyl
Grignard Reagent Leading to Allylsilanes or Alkene"
Jun Terao, Hiroyasu Watabe, Hiroyuki Watanabe and Nobuaki Kambe
Adv. Synth. Catal., 346
(13-15), 1674-1678
(2004)
"Cross-Coupling Reaction of Alkyl Halides with Organometallic Reagents
Using Transition-Metal Catalysts"
Jun Terao and Nobuaki Kambe
J. Synth. Org. Chem. Jpn.,
62 (12), 1192-1204
(2004)
"Nickel-Catalyzed Cross-coupling Reaction of Alkyl Halides with
Organozinc and Grignard Reagents Using 1,3,8,10-Tetraenes as Additives"
Jun Terao, Hirohisa Todo, Hideyuki Watanabe, Aki Ikumi and Nobuaki Kambe
Angew. Chem., Int. Ed.,
43 (45), 6180-6182
(2004)
"Palladium-Catalyzed Dimerizative Disilylation of 1,3-Butadiene with
Chlorosilane"
Jun Terao, Akihiro Oda and Nobuaki Kambe
Org. Lett., 6 (19),
3341-3344 (2004)
"Nickel-Catalyzed Regioselective Three Component Coupling Reaction of
Alkyl Halides, Butadienes, and Ar-M (M = MgX, ZnX)"
Jun Terao, Shinsuke Nii, Firoz A. Chowdhury, Akifumi Nakamura and
Nobuaki Kambe
Adv. Synth. Catal., 346
(8), 905-908 (2004)
"Pt-Catalyzed Regio- and Stereoselective Thienylthiolation of Alkynes"
Takayoshi Hirai, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 33 (9),
1148-1149 (2004)
"Selenoimidoylation of Alcohols with Selenium and Isocyanides and Its
Application to the Synthesis of Selenium-Containing Heterocycles"
Yoshiaki Asanuma, Shin-ichi Fujiwara, Tsutomu Shin-ike and Nobuaki Kambe
J. Org. Chem., 69 (14),
4845-4848 (2004)
"Carbonylation of Lithium Enolates with Carbon Monoxide Mediated by
Selenium"
Shin-ichi Fujiwara, Akira Nishiyama, Tsutomu Shin-ike, Nobuaki Kambe
and Noboru Sonoda
Org. Lett., 6 (3),
453-455 (2004)
"Titanocene-Catalyzed Formation of Allylsilanes from Allyl Ethers and
Chlorosilanes"
Shinsuke Nii, Jun Terao and Nobuaki Kambe
Tetrahedron
Lett., 45 (8), 1699-1702 (2004)
"1,3-Butadiene as an Efficient Additive for Nickel, Palladium, or
Copper-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Grignard
Reagents"
Jun Terao and Nobuaki Kambe
"Catalysts for Fine Chemical Synthesis, Vol. 3, Metal
Catalysed
Carbon-Carbon Bond-Forming Reactions", S. M. Roberts, J.
Whittall,
P. Mather, and P. McCormack (Eds.), John
Wiley & Sons, Oxford, 128-133 (2004)
"Titanocene-Catalyzed Regioselective Carbomagnesation of Alkenes and
Dienes"
Shinsuke Nii, Jun Terao and Nobuaki Kambe
J. Org. Chem., 69 (2),
573-576 (2004)
"Reaction Pathways of Zirconocene-Catalyzed Silylation of Alkenes with
Chlorosilanes"
Jun Terao, Yingshi Jin, Kazushi Torii and Nobuaki Kambe
Tetrahedron,
60 (6), 1301-1308 (2004)
"アート型遷移金属錯体の創製と触媒反応への展開
炭素－炭素および炭素－ケイ素結合生成の新手法の開発を目指して
"
寺尾 潤
化学と工業, 67 (2), 115-118 (2004)
"Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki
coupling"
Jun Terao, Andrew Tang, Jasper J. Michels, Alexander Krivokapic and
Harry L. Anderson
Chem. Commun., (1), 56-57
(2004)
"Nickel-Catalyzed
Dimerizative Carbosilylation of
1,3-Butadienes with Chlorosilanes and Grignard Reagents"
Jun Terao, Akihiro Oda, Aki Ikumi, Akifumi Nakamura, Hitoshi Kuniyasu
and Nobuaki Kambe
Angew. Chem., Int. Ed. Engl.,
42 (29),
3412-3414
(2003)
"Ni- or Cu-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with
Grignard Reagents"
Jun Terao, Aki Ikumi, Hitoshi Kuniyasu and Nobuaki Kambe
J. Am. Chem. Soc., 125
(19), 5646-5647 (2003)
"Titanocene-Catalyzed Alkylation of Aryl-substituted Alkenes with Alkyl
Halides"
Jun Terao, Hiroyasu Watabe, Masako Miyamoto and Nobuaki Kambe
Bull. Chem. Soc. Jpn., 76
(11), 2209-2214 (2003)
"The Pt-Catalyzed Carboselenation of Alkynes by Selenoesters"
Takayoshi Hirai, Hitoshi Kuniyasu, Tomohiro Kato, Yumi Kurata and
Nobuaki Kambe
Org. Lett., 5 (21),
3871-3873 (2003)
"Pd-catalyzed Cross-coupling Reaction of Alkyl Tosylates and Bromides
with Grignard Reagents in the Presence of 1,3-Butadiene"
Jun Terao, Yoshitaka Naitoh, Hitoshi Kuniyasu and Nobuaki Kambe
Chem. Lett., 32 (10),
890-891 (2003)
"Nickel-Catalyzed
Cross-Coupling Reaction of
Grignard
Reagents
with Alkyl Halides and Tosylates: Remarkable Effect of 1,3-Butadienes"
Jun Terao, Hideyuki Watanabe, Aki Ikumi, Hitoshi Kuniyasu, Nobuaki Kambe
J. Am. Chem. Soc., 124
(16), 4222-4223 (2002)
"Zirconocene- or Titanocene Catalyzed Reactions Using Grignard Reagents"
Jun Terao and Nobuaki Kambe
in "Latest Frontiers of Organic Synthesis", Y.
Kobayashi (Ed.),
Research Signpost, India, 25-47 (2002)
"Stereoselective Synthesis of New Selenium-Containing Heterocycles
byCyclocarbonylation of Aminoalkynes with Carbon Monoxide and Selenium"
Shin-ichi Fujiwara, Yasukazu Shikano, Tsutomu Shin-ike, Nobuaki Kambe
and Noboru Sonoda
J. Org. Chem., 67 (17),
6275-6278 (2002)
"Titanocene-Catalyzed
Reaction of Alkenes and
Dienes
with
Alkyl Halides and Chlorosilanes"
Jun Terao and Nobuaki Kambe
"Journal of Synthetic Organic Chemistry Japan (Special Issue
in
English)", 59(11), 1044-1051 (2001)
"A Prototype of Transition-Metal-Catalyzed Carbothiolation of Alkynes"
Kunihiko Sugoh, Hitoshi Kuniyasu, Taeko Sugae, Atsushi Ohtaka, Yasutomo
Takai, Aoi Tanaka, Chikako Machino, Nobuaki Kambe and Hideo Kurosawa
J. Am. Chem. Soc., 123
(21), 5108-5109 (2001)
"Photoinduced Group Transfer Radical Addition of Carbamotelluroloates
to Acetylenes"
Shin-ichi Fujiwara, Yoshihiko Shimizu, Tsutomu Shin-ike and Nobuaki
Kambe
Org. Lett., 3 (13),
2085-2088 (2001)
"Formation of 1,4-Disilyl-2-butenes from Vinyl Grignard Reagent and
Chlorosilanes Catalyzed by a Titanocene Comples"
Hiroyasu Watabe, Jun Terao and Nobuaki Kambe
Org. Lett., 3(11),
1733-1735 (2001).
"Imidoyl Radicals as Synthons of Unstable Acyl Radicals"
Shin-ichi Fujiwara, Takahiro Matsuya, Hajime Maeda, Tsutomu Shin-ike,
Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 66 (6),
2183-2185 (2001)
"
Nickel-Catalyzed Dimerization and
Alkylarylation of 1,3-Dienes with Alkyl Fluorides and
Aryl Grignard Reagents
"
Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, Nobuaki
Kambe
"Imidoylation of Acidic Hydrocarbons with Selenium and Isocyanides: A
New Synthetic Method for Preparation of Selenoimides"
Shin-ichi Fujiwara, Hajime Maeda, Takahiro Matsuya, Tsutomu Shin-ike,
Nobuaki Kambe and Noboru Sonoda
J. Org. Chem., 65 (16),
5022-5025 (2000)
"The key to the Oxidative Addition of Vinyl Sulfide to M(0)"
Hitoshi Kuniyasu, Atushi Ohtaka, Takeo Nakazono, Masanori Kinomoto and
Hideo Kurosawa
J. Am. Chem. Soc., 122
(10), 2375-2376 (2000)